The DOI matches its Crossref record; 21 of the 21 references it cites were found in a registry or an index.
Design of a Solid Electrolyte Interphase for Aqueous Zn Batteries
Abstract
Aqueous Zn batteries are challenged by water decomposition and dendrite growth due to the absence of a dense Zn‐ion conductive solid electrolyte interphase (SEI) to inhibit the hydrogen evolution reaction (HER). Here, we design a low‐concentration aqueous Zn(OTF)2‐Zn(NO 3)2 electrolyte to in situ form a robust inorganic ZnF 2‐Zn 5(CO 3)2(OH)6‐organic bilayer SEI, where the inorganic inner layer promotes Zn‐ion diffusion while the organic outer layer suppresses water penetration. We found that the insulating Zn 5(OH)8(NO 3)2⋅2 H 2 O layer is first formed on the Zn anode surface by the self‐terminated chemical reaction of NO 3− with Zn 2+ and OH− generated via HER, and then it transforms into Zn‐ion conducting Zn 5(CO 3)2(OH)6, which in turn promotes the formation of ZnF 2 as the inner layer. The organic‐dominated outer layer is formed by the reduction of OTF−. The in situ formed SEI enables a high Coulombic efficiency (CE) of 99.8 % for 200 h in Ti∥Zn cells, and a high energy density (168 Wh kg−1) with 96.5 % retention for 700 cycles in Zn∥MnO 2 cells with a low Zn/MnO 2 capacity ratio of 2:1.
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Kundu, D., Adams, B. D., Duffort, V., Vajargah, S. H., & Nazar, L. F. (2016) · Nature Energy · doi:10.1038/nenergy.2016.119 · Cited by 3,124
Issues and opportunities facing aqueous zinc-ion batteries
Tang, B., Shan, L., Liang, S., & Zhou, J. (2019) · Energy & Environmental Science · doi:10.1039/c9ee02526j · Cited by 2,182
Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities
Zhang, N., Cheng, F., Liu, J., Wang, L., Long, X., Liu, X., Li, F., & Chen, J. (2017) · Nature Communications · doi:10.1038/s41467-017-00467-x · Cited by 1,796
Kang, L., Cui, M., Jiang, F., Gao, Y., Luo, H., Liu, J., Liang, W., & Zhi, C. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201801090 · Cited by 1,245
Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation
Qiu, H., Du, X., Zhao, J., Wang, Y., Ju, J., Chen, Z., Hu, Z., Yan, D., Zhou, X., & Cui, G. (2019) · Nature Communications · doi:10.1038/s41467-019-13436-3 · Cited by 953
Yang, H., Chang, Z., Qiao, Y., Deng, H., Mu, X., He, P., & Zhou, H. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202001844 · Cited by 845
Aqueous vs. nonaqueous Zn-ion batteries: consequences of the desolvation penalty at the interface
Kundu, D., Hosseini Vajargah, S., Wan, L., Adams, B., Prendergast, D., & Nazar, L. F. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00378e · Cited by 833
High performance platinum single atom electrocatalyst for oxygen reduction reaction
Liu, J., Jiao, M., Lu, L., Barkholtz, H. M., Li, Y., Wang, Y., Jiang, L., Wu, Z., Liu, D.-J., Zhuang, L., et al. (2017) · Nature Communications · doi:10.1038/ncomms15938 · Cited by 772
Advanced High‐Voltage Aqueous Lithium‐Ion Battery Enabled by “Water‐in‐Bisalt” Electrolyte
Suo, L., Borodin, O., Sun, W., Fan, X., Yang, C., Wang, F., Gao, T., Ma, Z., Schroeder, M., von Cresce, A., et al. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201602397 · Cited by 746
Self-citationHighly Reversible and Rechargeable Safe Zn Batteries Based on a Triethyl Phosphate Electrolyte
Naveed, A., Yang, H., Yang, J., Nuli, Y., & Wang, J. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201813223 · Cited by 530
Cited by
Insight on Organic Molecules in Aqueous Zn‐Ion Batteries with an Emphasis on the Zn Anode Regulation
Wang, D., Li, Q., Zhao, Y., Hong, H., Li, H., Huang, Z., Liang, G., Yang, Q., & Zhi, C. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202102707 · Cited by 478
Halogenated Zn2+ Solvation Structure for Reversible Zn Metal Batteries
Zhang, Q., Ma, Y., Lu, Y., Ni, Y., Lin, L., Hao, Z., Yan, Z., Zhao, Q., & Chen, J. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c06927 · Cited by 426
Metadata
- Authors
- Li, D., Cao, L., Deng, T., Liu, S., & Wang, C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2021-05-05
- Volume
- 60
- Issue
- 23
- Pages
- 13035-13041
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3152376975
- Cited by
- 466
- References
- 21
- FWCI
- 23.98
- Type
- journal article
- Language
- en
- Open access
- closed
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