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Atomic Structure Modification for Electrochemical Nitrogen Reduction to Ammonia
Abstract
The electrochemical nitrogen reduction reaction (NRR), as an environmentally friendly method to convert nitrogen to ammonia at ambient temperature and pressure, has attracted the attention of numerous researchers. However, when compared with industrial production, electrochemical NRR often suffers from unsatisfactory yields and poor Faraday efficiency (FE). Recently, various structure engineering strategies have aimed to introduce extra active sites or enhance intrinsic activity to optimize the activation and hydrogenation of N 2. In this review, recent progress in atomic structure modification is summarized and discussed to design high‐efficiency NRR catalysts, with a focus on defect engineering (heteroatom doping and atom vacancy), surface orientation and amorphization, as well as heterostructure engineering. In addition, existing challenges and future development directions are proposed to obtain more credible NRR catalysts with high catalytic performance and selectivity.
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Cites
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747
Montoya, J. H., Tsai, C., Vojvodic, A., & Nørskov, J. K. (2015) · ChemSusChem · doi:10.1002/cssc.201500322 · Cited by 1,384
Xie, H., Wang, H., Geng, Q., Xing, Z., Wang, W., Chen, J., Ji, L., Chang, L., Wang, Z., & Mao, J. (2019) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.9b00622 · Cited by 112
Cited by
High-entropy alloys in electrocatalysis: from fundamentals to applications
Ren, J.-T., Chen, L., Wang, H.-Y., & Yuan, Z.-Y. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00557g · Cited by 551
Wu, Y., Li, Y., Gao, J., & Zhang, Q. (2021) · SusMat · doi:10.1002/sus2.3 · Cited by 319
Synthesis Strategies, Catalytic Applications, and Performance Regulation of Single‐Atom Catalysts
Xi, J., Jung, H. S., Xu, Y., Xiao, F., Bae, J. W., & Wang, S. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202008318 · Cited by 282
Metadata
- Authors
- Chen, X., Guo, Y., Du, X., Zeng, Y., Chu, J., Gong, C., Huang, J., Fan, C., Wang, X., & Xiong, J.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2019-12-11
- Volume
- 10
- Issue
- 3
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2994700550
- Cited by
- 159
- References
- 3
- FWCI
- 4.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, X., Guo, Y., Du, X., Zeng, Y., Chu, J., Gong, C., Huang, J., Fan, C., Wang, X., & Xiong, J. (2020). Atomic Structure Modification for Electrochemical Nitrogen Reduction to Ammonia. Advanced Energy Materials. https://doi.org/10.1002/aenm.201903172
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