Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels

Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode

Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153

Combining theory and experiment in electrocatalysis: Insights into materials design

Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114

Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction

McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026

Modern Aspects of Electrochemistry

Bockris, J. O., White, R. E., & Conway, B. E. (2002) · Kluwer Academic Publishers eBooks · doi:10.1007/b114168 · Cited by 5,954

How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels

Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces

Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160

CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface

Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515

Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide

Kortlever, R., Shen, J., Schouten, K. J. P., Calle‐Vallejo, F., & Koper, M. T. M. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01559 · Cited by 2,214

Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media

Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140

CO 2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu 2 O Films

Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000

Real surface area measurements in electrochemistry

Trasatti, S. P. M., & Петрий, О. А. (1991) · Pure and Applied Chemistry · doi:10.1351/pac199163050711 · Cited by 1,836

Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper

Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728

Scaling Properties of Adsorption Energies for Hydrogen-Containing Molecules on Transition-Metal Surfaces

Abild-Pedersen, F., Greeley, J., Studt, F., Rossmeisl, J., Munter, T. R., Moses, P. G., Skúlason, E., Bligaard, T., & Nørskov, J. K. (2007) · Physical Review Letters · doi:10.1103/physrevlett.99.016105 · Cited by 1,678

Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts

Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667

Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles

Chen, Y., Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309317u · Cited by 1,661

Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution

Hori, Y., Murata, A., & Takahashi, R. (1989) · Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · doi:10.1039/f19898502309 · Cited by 1,644

What Should We Make with CO2 and How Can We Make It?

Bushuyev, O. S., De Luna, P., Dinh, C. T., Tao, L., Saur, G., van de Lagemaat, J., Kelley, S. O., & Sargent, E. H. (2018) · Joule · doi:10.1016/j.joule.2017.09.003 · Cited by 1,593

A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper

Gattrell, M., Gupta, N., & Co, A. C. (2006) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.05.013 · Cited by 1,482

Particle Size Effects in the Catalytic Electroreduction of CO2 on Cu Nanoparticles

Reske, R., Mistry, H., Behafarid, F., Cuenya, B. R., & Strasser, P. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500328k · Cited by 1,452

Prospects of CO 2 Utilization via Direct Heterogeneous Electrochemical Reduction

Whipple, D. T., & Kenis, P. J. A. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1012627 · Cited by 1,419

Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO 2 to CO

Zhu, W., Michalsky, R., Metin, Ö., Lv, H., Guo, S., Wright, C. J., Sun, X., Peterson, A. A., & Sun, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409445p · Cited by 1,391

Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide

Resasco, J., Chen, L. D., Clark, E. L., Tsai, C., Hahn, C., Jaramillo, T. F., Chan, K., & Bell, A. T. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06765 · Cited by 1,218

Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene

Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214

Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO 2 over Ag and Cu

Singh, M. R., Kwon, Y., Lum, Y., Ager, J. W., & Bell, A. T. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07612 · Cited by 985

A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes

Schouten, K. J. P., Kwon, Y., van der Ham, C. J. M., Qin, Z., & Koper, M. T. M. (2011) · Chemical Science · doi:10.1039/c1sc00277e · Cited by 972

Mechanism of CO2 Reduction at Copper Surfaces: Pathways to C2 Products

Garza, A. J., Bell, A. T., & Head‐Gordon, M. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03477 · Cited by 956

Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes

Calle‐Vallejo, F., & Koper, M. T. M. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201301470 · Cited by 941

Selectivity of CO 2 Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps

Nie, X., Esopi, M. R., Janik, M. J., & Asthagiri, A. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201208320 · Cited by 940

Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts

Ren, D., Deng, Y., Handoko, A. D., Chen, C. S., Malkhandi, S., & Yeo, B. S. (2015) · ACS Catalysis · doi:10.1021/cs502128q · Cited by 930

Two Pathways for the Formation of Ethylene in CO Reduction on Single-Crystal Copper Electrodes

Schouten, K. J. P., Qin, Z., Pérez‐Gallent, E., & Koper, M. T. M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302668n · Cited by 904

Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction

Loiudice, A., Lobaccaro, P., Kamali, E. A., Thao, T., Huang, B. H., Ager, J. W., & Buonsanti, R. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601582 · Cited by 896

Theoretical Insights into a CO Dimerization Mechanism in CO 2 Electroreduction

Montoya, J. H., Shi, C., Chan, K., & Nørskov, J. K. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b00722 · Cited by 867

Direct Observation on Reaction Intermediates and the Role of Bicarbonate Anions in CO 2 Electrochemical Reduction Reaction on Cu Surfaces

Zhu, S., Jiang, B., Cai, W., & Shao, M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10462 · Cited by 861

Nanoporous Copper–Silver Alloys by Additive-Controlled Electrodeposition for the Selective Electroreduction of CO2 to Ethylene and Ethanol

Hoang, T. T. H., Verma, S., Ma, S., Fister, T. T., Timoshenko, J., Frenkel, A. I., Kenis, P. J. A., & Gewirth, A. A. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b01868 · Cited by 852

Metal ion cycling of Cu foil for selective C–C coupling in electrochemical CO2 reduction

Jiang, K. P., Sandberg, R. B., Akey, A. J., Liu, X., Bell, D. C., Nørskov, J. K., Chan, K., & Wang, H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0009-x · Cited by 845

Selective increase in CO 2 electroreduction activity at grain-boundary surface terminations

Mariano, R. G., McKelvey, K., White, H. S., & Kanan, M. W. (2017) · Science · doi:10.1126/science.aao3691 · Cited by 818

Electrochemical reduction of carbon dioxide at various series of copper single crystal electrodes

Hori, Y., Takahashi, I., Koga, O., & Hoshi, N. (2003) · Journal of Molecular Catalysis A Chemical · doi:10.1016/s1381-1169(03)00016-5 · Cited by 762

Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO 2 Reduction to CO

Hansen, H. A., Varley, J. B., Peterson, A. A., & Nørskov, J. K. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz3021155 · Cited by 759

Understanding heterogeneous electrocatalytic carbon dioxide reduction through operando techniques

Handoko, A. D., Wei, F., Jenndy, Yeo, B. S., & Seh, Z. W. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0182-6 · Cited by 747

Tuning the Selectivity of Carbon Dioxide Electroreduction toward Ethanol on Oxide-Derived Cu x Zn Catalysts

Ren, D., Ang, B. S.-H., & Yeo, B. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02162 · Cited by 733

The Central Role of Bicarbonate in the Electrochemical Reduction of Carbon Dioxide on Gold

Dunwell, M., Lu, Q., Heyes, J., Rosen, J., Chen, J. G., Yan, Y. S., Jiao, F., & Xu, B. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b13287 · Cited by 718

Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO 2 : New Theoretical Insights from an Improved Electrochemical Model

Goodpaster, J. D., Bell, A. T., & Head-Gordon, M. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00358 · Cited by 702

Electric Field Effects in Electrochemical CO 2 Reduction

Chen, L. D., Urushihara, M., Chan, K., & Nørskov, J. K. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02299 · Cited by 702

The importance of surface morphology in controlling the selectivity of polycrystalline copper for CO2 electroreduction

Tang, W., Peterson, A. A., Varela, A. S., Jovanov, Z. P., Bech, L., Durand, W. J., Dahl, S., Nørskov, J. K., & Chorkendorff, I. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp22700a · Cited by 697

Exceptional Size-Dependent Activity Enhancement in the Electroreduction of CO2 over Au Nanoparticles

Mistry, H., Reske, R., Zeng, Z., Zhao, Z.-J., Greeley, J., Strasser, P., & Cuenya, B. R. (2014) · Journal of the American Chemical Society · doi:10.1021/ja508879j · Cited by 690

Surface Pourbaix diagrams and oxygen reduction activity of Pt, Ag and Ni(111) surfaces studied by DFT

Hansen, H. A., Rossmeisl, J., & Nørskov, J. K. (2008) · Physical Chemistry Chemical Physics · doi:10.1039/b803956a · Cited by 667

Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts

Verdaguer-Casadevall, A., Li, C. W., Johansson, T. P., Scott, S. B., McKeown, J. T., Kumar, M., Stephens, I. E. L., Kanan, M. W., & Chorkendorff, I. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06227 · Cited by 645

pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper

Liu, X., Schlexer, P., Xiao, J., Ji, Y., Wang, L., Sandberg, R. B., Tang, M. T., Brown, K. S., Peng, H., Ringe, S., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-07970-9 · Cited by 645

Toward a Low‐Cost Artificial Leaf: Driving Carbon‐Based and Bifunctional Catalyst Electrodes with Solution‐Processed Perovskite Photovoltaics

Sharifi, T., Larsen, C., Wang, J., Kwong, W. L., Gracia‐Espino, E., Mercier, G., Messinger, J., Wågberg, T., & Edman, L. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600738 · Cited by 642

Spectroscopic Observation of a Hydrogenated CO Dimer Intermediate During CO Reduction on Cu(100) Electrodes

Pérez‐Gallent, E., Figueiredo, M. C., Calle‐Vallejo, F., & Koper, M. T. M. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201700580 · Cited by 640

Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin

Shen, J., Kortlever, R., Kaş, R., Birdja, Y. Y., Díaz‐Morales, O., Kwon, Y., Ledezma‐Yanez, I., Schouten, K. J. P., Mul, G., & Koper, M. T. M. (2015) · Nature Communications · doi:10.1038/ncomms9177 · Cited by 612

Efficient Electrochemical Reduction of Carbon Dioxide to Acetate on Nitrogen-Doped Nanodiamond

Liu, Y., Chen, S., Quan, X., & Yu, H. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b02975 · Cited by 602

Insights into the electrocatalytic reduction of CO 2 on metallic silver surfaces

Hatsukade, T., Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp00692e · Cited by 576

Copper nanocavities confine intermediates for efficient electrosynthesis of C3 alcohol fuels from carbon monoxide

Zhuang, T., Pang, Y., Liang, Z.-Q., Wang, Z., Li, Y., Tan, C., Li, J., Dinh, C., Luna, P. D., Hsieh, P., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0168-4 · Cited by 561

Calculation for the cathode surface concentrations in the electrochemical reduction of CO2 in KHCO3 solutions

Gupta, N., Gattrell, M., & MacDougall, B. (2006) · Journal of Applied Electrochemistry · doi:10.1007/s10800-005-9058-y · Cited by 558

Electrochemical CO 2 reduction on Cu 2 O-derived copper nanoparticles: controlling the catalytic selectivity of hydrocarbons

Kaş, R., Kortlever, R., Milbrat, A., Koper, M. T. M., Mul, G., & Baltrušaitis, J. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp01520g · Cited by 550

Product Selectivity Affected by Cationic Species in Electrochemical Reduction of CO2 and CO at a Cu Electrode

Murata, A., & Hori, Y. (1991) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.64.123 · Cited by 544

Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH

Varela, A. S., Kroschel, M., Reier, T., & Strasser, P. (2016) · Catalysis Today · doi:10.1016/j.cattod.2015.06.009 · Cited by 542

Pd-Catalyzed Electrohydrogenation of Carbon Dioxide to Formate: High Mass Activity at Low Overpotential and Identification of the Deactivation Pathway

Min, X., & Kanan, M. W. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511890h · Cited by 541

Electrochemical Reduction of CO2 at Copper Nanofoams

Sen, S., Liu, D., & Palmore, G. T. R. (2014) · ACS Catalysis · doi:10.1021/cs500522g · Cited by 537

Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide‐Derived Nanostructured Silver Electrocatalysts

Ma, M., Trześniewski, B. J., Xie, J., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604654 · Cited by 530

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts

Roberts, F. S., Kuhl, K. P., & Nilsson, A. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201412214 · Cited by 521

Subsurface oxide plays a critical role in CO 2 activation by Cu(111) surfaces to form chemisorbed CO 2 , the first step in reduction of CO 2

Favaro, M., Xiao, H. Y., Cheng, T., Goddard, W. A., Yano, J., & Crumlin, E. J. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1701405114 · Cited by 519

Mesostructure-Induced Selectivity in CO2 Reduction Catalysis

Hall, A. S., Yoon, Y., Wuttig, A., & Surendranath, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08259 · Cited by 511

Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces

Le, M., Ren, M.-Y., Zhang, Z., Sprunger, P. T., Kurtz, R. L., & Flake, J. C. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3561636 · Cited by 500

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts

Roberts, F. S., Kuhl, K. P., & Nilsson, A. (2015) · Angewandte Chemie · doi:10.1002/ange.201412214 · Cited by 494

Tuning the Catalytic Activity and Selectivity of Cu for CO 2 Electroreduction in the Presence of Halides

Varela, A. S., Ju, W., Reier, T., & Strasser, P. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02550 · Cited by 492

Electrochemical Barriers Made Simple

Chan, K., & Nørskov, J. K. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01043 · Cited by 486

CO2 Electrochemical Reduction As Probed through Infrared Spectroscopy

Zhu, S., Li, T., Cai, W., & Shao, M. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.8b02525 · Cited by 473

Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO 2 Electroreduction by Process Conditions

Kas, R., Kortlever, R., Yılmaz, H., Koper, M. T. M., & Mul, G. (2015) · ChemElectroChem · doi:10.1002/celc.201402373 · Cited by 464

A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles

Feng, X., Jiang, K., Fan, S., & Kanan, M. W. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00022 · Cited by 460

Morphology Matters: Tuning the Product Distribution of CO2 Electroreduction on Oxide-Derived Cu Foam Catalysts

Dutta, A., Rahaman, M., Lüdi, N., Mohos, M., & Broekmann, P. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00770 · Cited by 460

Atomistic Mechanisms Underlying Selectivities in C1 and C2 Products from Electrochemical Reduction of CO on Cu(111)

Xiao, H., Cheng, T., & Goddard, W. A. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06846 · Cited by 458

Electrochemical CO2 Reduction to Formic Acid at Low Overpotential and with High Faradaic Efficiency on Carbon-Supported Bimetallic Pd–Pt Nanoparticles

Kortlever, R., Peters, I., Koper, S., & Koper, M. T. M. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00602 · Cited by 457

Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction

Eilert, A., Cavalca, F., Roberts, F. S., Osterwalder, J., Liu, C., Favaro, M., Crumlin, E. J., Ogasawara, H., Friebel, D., Pettersson, L. G. M., et al. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02273 · Cited by 443

Competition between Hydrogen Evolution and Carbon Dioxide Reduction on Copper Electrodes in Mildly Acidic Media

Ooka, H., Figueiredo, M. C., & Koper, M. T. M. (2017) · Langmuir · doi:10.1021/acs.langmuir.7b00696 · Cited by 440

Theoretical Insight into the Trends that Guide the Electrochemical Reduction of Carbon Dioxide to Formic Acid

Yoo, J. S., Christensen, R., Vegge, T., Nørskov, J. K., & Studt, F. (2015) · ChemSusChem · doi:10.1002/cssc.201501197 · Cited by 435

Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide

Singh, M. R., Clark, E. L., & Bell, A. T. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp03283k · Cited by 427

Electrochemical CO2 Reduction: Recent Advances and Current Trends

Jones, J., Prakash, G. K. S., & Olah, G. A. (2014) · Israel Journal of Chemistry · doi:10.1002/ijch.201400081 · Cited by 425

Inhibited proton transfer enhances Au-catalyzed CO 2 -to-fuels selectivity

Wuttig, A., Yaguchi, M., Motobayashi, K., Osawa, M., & Surendranath, Y. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1602984113 · Cited by 423

Theoretical Heterogeneous Catalysis: Scaling Relationships and Computational Catalyst Design

Greeley, J. (2016) · Annual Review of Chemical and Biomolecular Engineering · doi:10.1146/annurev-chembioeng-080615-034413 · Cited by 418

Engineering Cu surfaces for the electrocatalytic conversion of CO 2 : Controlling selectivity toward oxygenates and hydrocarbons

Hahn, C., Hatsukade, T., Kim, Y.-G., Vailionis, A., Baricuatro, J. H., Higgins, D. C., Nitopi, S. A., Soriaga, M. P., & Jaramillo, T. F. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1618935114 · Cited by 417

Structure- and Potential-Dependent Cation Effects on CO Reduction at Copper Single-Crystal Electrodes

Pérez‐Gallent, E., Marcandalli, G., Figueiredo, M. C., Calle‐Vallejo, F., & Koper, M. T. M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10142 · Cited by 415

Stability of Residual Oxides in Oxide‐Derived Copper Catalysts for Electrochemical CO2 Reduction Investigated with 18O Labeling

Lum, Y., & Ager, J. W. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710590 · Cited by 410

How strain can break the scaling relations of catalysis

Khorshidi, A., Violet, J., Hashemi, J., & Peterson, A. A. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0054-0 · Cited by 409

Recent Advances in Breaking Scaling Relations for Effective Electrochemical Conversion of CO2

Li, Y., & Sun, Q. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600463 · Cited by 390

Lattice-Hydride Mechanism in Electrocatalytic CO 2 Reduction by Structurally Precise Copper-Hydride Nanoclusters

Tang, Q. H., Lee, Y., Li, D.-Y., Choi, W., Liu, C. W., Lee, D., & Jiang, D. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05591 · Cited by 384

Reversibility and efficiency in electrocatalytic energy conversion and lessons from enzymes

Armstrong, F. A., & Hirst, J. (2011) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1103697108 · Cited by 378

Three-dimensional porous hollow fibre copper electrodes for efficient and high-rate electrochemical carbon dioxide reduction

Kaş, R., Hummadi, K. K., Kortlever, R., de Wit, P., Milbrat, A., Luiten-Olieman, M. W. J., Benes, N. E., Koper, M. T. M., & Mul, G. (2016) · Nature Communications · doi:10.1038/ncomms10748 · Cited by 372

Structure Sensitivity of the Electrochemical Reduction of Carbon Monoxide on Copper Single Crystals

Schouten, K. J. P., Pérez‐Gallent, E., & Koper, M. T. M. (2013) · ACS Catalysis · doi:10.1021/cs4002404 · Cited by 370

Standards and Protocols for Data Acquisition and Reporting for Studies of the Electrochemical Reduction of Carbon Dioxide

Clark, E. L., Resasco, J., Landers, A. T., Lin, J. C., Chung, L.-T., Walton, A., Hahn, C., Jaramillo, T. F., & Bell, A. T. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01340 · Cited by 368

Effect of Cations on the Electrochemical Conversion of CO2to CO

Thorson, M. R., Siil, K. I., & Kenis, P. J. A. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.052301jes · Cited by 364

Morphology‐Directed Selective Production of Ethylene or Ethane from CO2 on a Cu Mesopore Electrode

Yang, K. D., Ko, W. R., Lee, J., Kim, S. J., Lee, H., Lee, M. H., & Nam, K. T. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201610432 · Cited by 358

Stable and selective electrochemical reduction of carbon dioxide to ethylene on copper mesocrystals

Chen, C. S., Handoko, A. D., Wan, J. H., Ma, L., Ren, D., & Yeo, B. S. (2014) · Catalysis Science & Technology · doi:10.1039/c4cy00906a · Cited by 352

Controlling H + vs CO 2 Reduction Selectivity on Pb Electrodes

Lee, C. H., & Kanan, M. W. (2014) · ACS Catalysis · doi:10.1021/cs5017672 · Cited by 347

Spectroscopic Observation of Reversible Surface Reconstruction of Copper Electrodes under CO2 Reduction

Gunathunge, C. M., Li, X., Li, J., Hicks, R. P., Ovalle, V. J., & Waegele, M. M. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b03910 · Cited by 345

Improved CO 2 Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect

Gao, D., Scholten, F., & Cuenya, B. R. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01416 · Cited by 343

High‐Selectivity Electrochemical Conversion of CO 2 to Ethanol using a Copper Nanoparticle/N‐Doped Graphene Electrode

Song, Y., Peng, R., Hensley, D. K., Bonnesen, P. V., Liang, L., Wu, Z., Meyer, H. M., Chi, M., Ma, C., Sumpter, B. G., et al. (2016) · ChemistrySelect · doi:10.1002/slct.201601169 · Cited by 328

The effects of currents and potentials on the selectivities of copper toward carbon dioxide electroreduction

Ren, D., Fong, J., & Yeo, B. S. (2018) · Nature Communications · doi:10.1038/s41467-018-03286-w · Cited by 327

Tracking a Common Surface-Bound Intermediate during CO 2 -to-Fuels Catalysis

Wuttig, A., Liu, C., Peng, Q., Yaguchi, M., Hendon, C. H., Motobayashi, K., Ye, S., Osawa, M., & Surendranath, Y. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00155 · Cited by 325

Electrocatalytic Production of C3‐C4 Compounds by Conversion of CO 2 on a Chloride‐Induced Bi‐Phasic Cu 2 O‐Cu Catalyst

Lee, S., Kim, D., & Lee, J. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201505730 · Cited by 320

CO2 Reduction Selective for C≥2 Products on Polycrystalline Copper with N-Substituted Pyridinium Additives

Han, Z., Kortlever, R., Chen, H., Peters, J. C., & Agapie, T. (2017) · ACS Central Science · doi:10.1021/acscentsci.7b00180 · Cited by 320

Scaling relations between adsorption energies for computational screening and design of catalysts

Montemore, M. M., & Medlin, J. W. (2014) · Catalysis Science & Technology · doi:10.1039/c4cy00335g · Cited by 315

Calculations of Product Selectivity in Electrochemical CO2 Reduction

Hussain, J., Jónsson, H., & Skúlason, E. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03308 · Cited by 314

Tuning of Silver Catalyst Mesostructure Promotes Selective Carbon Dioxide Conversion into Fuels

Yoon, Y., Hall, A. S., & Surendranath, Y. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201607942 · Cited by 311

Nickel–Gallium-Catalyzed Electrochemical Reduction of CO2 to Highly Reduced Products at Low Overpotentials

Torelli, D. A., Francis, S. A., Crompton, J. C., Javier, A., Thompson, J. R., Brunschwig, B. S., Soriaga, M. P., & Lewis, N. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02888 · Cited by 306

Mechanistic insights into electrochemical reduction of CO 2 over Ag using density functional theory and transport models

Singh, M. R., Goodpaster, J. D., Weber, A. Z., Head‐Gordon, M., & Bell, A. T. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1713164114 · Cited by 303

Mechanistic Insights into the Enhanced Activity and Stability of Agglomerated Cu Nanocrystals for the Electrochemical Reduction of Carbon Dioxide to n-Propanol

Ren, D., Wong, N. T., Handoko, A. D., Huang, Y., & Yeo, B. S. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b02554 · Cited by 283

In Situ Spectroscopic Study of CO 2 Electroreduction at Copper Electrodes in Acetonitrile

Figueiredo, M. C., Ledezma‐Yanez, I., & Koper, M. T. M. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02543 · Cited by 277

Bicarbonate Is Not a General Acid in Au-Catalyzed CO2 Electroreduction

Wuttig, A., Yoon, Y., Ryu, J., & Surendranath, Y. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b08345 · Cited by 273

Electrochemical CO2 reduction to C2+ species: Heterogeneous electrocatalysts, reaction pathways, and optimization strategies

Fan, Q., Zhang, M., Jia, M., Liu, S., Qiu, J., & Sun, Z. (2018) · Materials Today Energy · doi:10.1016/j.mtener.2018.10.003 · Cited by 272

Activity and Selectivity Control in CO2 Electroreduction to Multicarbon Products over CuOx Catalysts via Electrolyte Design

Gao, D., McCrum, I. T., Deo, S., Choi, Y.-W., Scholten, F., Wan, W., Chen, J. G., Janik, M. J., & Cuenya, B. R. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b02587 · Cited by 265

Challenges in Modeling Electrochemical Reaction Energetics with Polarizable Continuum Models

Gauthier, J. A., Ringe, S., Dickens, C. F., Garza, A. J., Bell, A. T., Head‐Gordon, M., Nørskov, J. K., & Chan, K. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b02793 · Cited by 258

Proton-coupled electron transfer in the electrocatalysis of CO 2 reduction: prediction of sequential vs. concerted pathways using DFT

Göttle, A. J., & Koper, M. T. M. (2016) · Chemical Science · doi:10.1039/c6sc02984a · Cited by 256

Spectroscopic Evidence of Size-Dependent Buffering of Interfacial pH by Cation Hydrolysis during CO 2 Electroreduction

Ayemoba, O., & Cuesta, Á. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b07351 · Cited by 256

Effects of Anion Identity and Concentration on Electrochemical Reduction of CO 2

Resasco, J., Lum, Y., Clark, E., Zeledon, J. Z., & Bell, A. T. (2018) · ChemElectroChem · doi:10.1002/celc.201701316 · Cited by 250

Selective CO 2 reduction to C 3 and C 4 oxyhydrocarbons on nickel phosphides at overpotentials as low as 10 mV

Calvinho, K. U. D., Laursen, A. B., Yap, K. M. K., Goetjen, T. A., Hwang, S., Murali, N., Mejia-Sosa, B., Lubarski, A., Teeluck, K. M., Hall, E. S., et al. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00936h · Cited by 241

Enhanced Carbon Dioxide Electroreduction to Carbon Monoxide over Defect‐Rich Plasma‐Activated Silver Catalysts

Mistry, H., Choi, Y., Bagger, A., Scholten, F., Bonifacio, C. S., Sinev, I., Divins, N. J., Zegkinoglou, I., Jeon, H. S., Kisslinger, K., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201704613 · Cited by 236

DFT Study on the Mechanism of the Electrochemical Reduction of CO 2 Catalyzed by Cobalt Porphyrins

Shen, J., Kolb, M. J., Göttle, A. J., & Koper, M. T. M. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b10763 · Cited by 227

Bond-Making and Breaking between Carbon, Nitrogen, and Oxygen in Electrocatalysis

Li, H., Li, Y., Koper, M. T. M., & Calle‐Vallejo, F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja508649p · Cited by 224

Insights into an autonomously formed oxygen-evacuated Cu 2 O electrode for the selective production of C 2 H 4 from CO 2

Kim, D., Lee, S., Ocon, J. D., Jeong, B., Lee, J. K., & Lee, J. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp03172e · Cited by 223

Probing the Mechanism of Aqueous CO2 Reduction on Post-Transition-Metal Electrodes using ATR-IR Spectroelectrochemistry

Pander, J. E., Baruch, M. F., & Bocarsly, A. B. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b01879 · Cited by 223

CO 2 Reduction on Cu at Low Overpotentials with Surface-Enhanced in Situ Spectroscopy

Heyes, J., Dunwell, M., & Xu, B. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b03065 · Cited by 221

Examination of Near-Electrode Concentration Gradients and Kinetic Impacts on the Electrochemical Reduction of CO 2 using Surface-Enhanced Infrared Spectroscopy

Dunwell, M., Yang, X., Setzler, B. P., Anibal, J., Yan, Y. S., & Xu, B. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01032 · Cited by 220

Electrochemical Reduction of CO 2 at Intentionally Oxidized Copper Electrodes

Frese, K. W. (1991) · Journal of The Electrochemical Society · doi:10.1149/1.2085411 · Cited by 216

Palladium–gold catalyst for the electrochemical reduction of CO 2 to C 1 –C 5 hydrocarbons

Kortlever, R., Peters, I., Balemans, C., Kaş, R., Kwon, Y., Mul, G., & Koper, M. T. M. (2016) · Chemical Communications · doi:10.1039/c6cc03717h · Cited by 200

Barriers of Electrochemical CO2 Reduction on Transition Metals

Shi, C., Chan, K., Yoo, J. S., & Nørskov, J. K. (2016) · Organic Process Research & Development · doi:10.1021/acs.oprd.6b00103 · Cited by 190

The Importance of Cannizzaro-Type Reactions during Electrocatalytic Reduction of Carbon Dioxide

Birdja, Y. Y., & Koper, M. T. M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b12008 · Cited by 187

Selective electrochemical reduction of CO 2 to CO on CuO-derived Cu nanowires

Ma, M., Djanashvili, K., & Smith, W. A. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp03559g · Cited by 185

Effect of CO2 Bubbling into Aqueous Solutions Used for Electrochemical Reduction of CO2 for Energy Conversion and Storage

Zhong, H., Fujii, K., Nakano, Y., & Jin, F. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp509043h · Cited by 184

Nature of the Active Sites for CO Reduction on Copper Nanoparticles; Suggestions for Optimizing Performance

Cheng, T., Xiao, H. Y., & Goddard, W. A. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03300 · Cited by 183

Electrochemical CO₂ Reduction – A Critical View on Fundamentals, Materials and Applications

Durst, J., Rudnev, A. V., Dutta, A., Fu, Y., Herranz, J. S., Kaliginedi, V., Kuzume, A., Permyakova, A. A., Paratcha, Y., Broekmann, P., et al. (2015) · CHIMIA International Journal for Chemistry · doi:10.2533/chimia.2015.769 · Cited by 174

Effects of Electrolyte Anions on the Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper (100) and (111) Surfaces

Huang, Y., Ong, C. W., & Yeo, B. S. (2018) · ChemSusChem · doi:10.1002/cssc.201801078 · Cited by 173

How covalence breaks adsorption-energy scaling relations and solvation restores them

Calle‐Vallejo, F., Krabbe, A., & García-Lastra, J. M. (2016) · Chemical Science · doi:10.1039/c6sc02123a · Cited by 172

Electrochemical CO 2 reduction on Au surfaces: mechanistic aspects regarding the formation of major and minor products

Cave, E. R., Montoya, J. H., Kuhl, K. P., Abram, D. N., Hatsukade, T., Shi, C., Hahn, C., Nørskov, J. K., & Jaramillo, T. F. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp02855e · Cited by 169

Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism

Solis, B. H., Maher, A. G., Dogutan, D. K., Nocera, D. G., & Hammes‐Schiffer, S. (2015) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1521834112 · Cited by 166

Structure-sensitive electroreduction of acetaldehyde to ethanol on copper and its mechanistic implications for CO and CO 2 reduction

Ledezma‐Yanez, I., Pérez‐Gallent, E., Koper, M. T. M., & Calle‐Vallejo, F. (2015) · Catalysis Today · doi:10.1016/j.cattod.2015.09.029 · Cited by 165

Mechanism of C–C bond formation in the electrocatalytic reduction of CO 2 to acetic acid. A challenging reaction to use renewable energy with chemistry

Genovese, C., Ampelli, C., Perathoner, S., & Centi, G. (2017) · Green Chemistry · doi:10.1039/c6gc03422e · Cited by 165

Tuning Catalytic Selectivity at the Mesoscale via Interparticle Interactions

Mistry, H., Behafarid, F., Reske, R., Varela, A. S., Strasser, P., & Cuenya, B. R. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b02202 · Cited by 163

Does the breaking of adsorption-energy scaling relations guarantee enhanced electrocatalysis?

Govindarajan, N., García-Lastra, J. M., Meijer, E. J., & Calle‐Vallejo, F. (2018) · Current Opinion in Electrochemistry · doi:10.1016/j.coelec.2018.03.025 · Cited by 159

Formation of Copper Catalysts for CO2 Reduction with High Ethylene/Methane Product Ratio Investigated with In Situ X-ray Absorption Spectroscopy

Eilert, A., Roberts, F. S., Friebel, D., & Nilsson, A. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00367 · Cited by 158

Understanding the Heterogeneous Electrocatalytic Reduction of Carbon Dioxide on Oxide‐Derived Catalysts

Pander, J. E., Ren, D., Huang, Y., Loo, N. W. X., Hong, S. H. L., & Yeo, B. S. (2017) · ChemElectroChem · doi:10.1002/celc.201701100 · Cited by 156

Selective electrochemical reduction of CO2 to ethylene at a three-phase interface on copper(I) halide-confined Cu-mesh electrodes in acidic solutions of potassium halides

Yano, H., Tanaka, T., Nakayama, M., & Ogura, K. (2003) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2003.10.021 · Cited by 153

Opportunities and challenges in the electrocatalysis of CO2 and CO reduction using bifunctional surfaces: A theoretical and experimental study of Au–Cd alloys

Jovanov, Z. P., Hansen, H. A., Varela, A. S., Malacrida, P., Peterson, A. A., Nørskov, J. K., Stephens, I. E. L., & Chorkendorff, I. (2016) · Journal of Catalysis · doi:10.1016/j.jcat.2016.04.008 · Cited by 152

Effects of Electrolyte Buffer Capacity on Surface Reactant Species and the Reaction Rate of CO 2 in Electrochemical CO 2 Reduction

Hashiba, H., Weng, L., Chen, Y., Sato, H., Yotsuhashi, S., Xiang, C., & Weber, A. Z. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b11316 · Cited by 151

Is Subsurface Oxygen Necessary for the Electrochemical Reduction of CO 2 on Copper?

Garza, A. J., Bell, A. T., & Head-Gordon, M. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b03180 · Cited by 148

CO2 attraction by specifically adsorbed anions and subsequent accelerated electrochemical reduction

Ogura, K., Ferrell, J. R., Cugini, A. V., Smotkin, E. S., & Salazar-Villalpando, M. D. (2010) · Electrochimica Acta · doi:10.1016/j.electacta.2010.08.065 · Cited by 146

Electrochemical carbon dioxide and bicarbonate reduction on copper in weakly alkaline media

Kortlever, R., Tan, K., Kwon, Y., & Koper, M. T. M. (2013) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-013-2100-9 · Cited by 141

Lizards on newly created islands independently and rapidly adapt in morphology and diet

de Amorim, M. E., Schoener, T. W., Santoro, G. R. C. C., Lins, A. C. R., Piovia‐Scott, J., & Brandão, R. A. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1709080114 · Cited by 141

Computational Comparison of Late Transition Metal (100) Surfaces for the Electrocatalytic Reduction of CO to C2 Species

Hanselman, S., Koper, M. T. M., & Calle‐Vallejo, F. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00326 · Cited by 136

Chemical, Structural, and Morphological Changes of a MoVTeNb Catalyst during Oxidative Dehydrogenation of Ethane

Valente, J. S., Armendáriz, H., Quintana, R., del Ángel, P., Nava, N., Massó, A., & Nieto, J. M. L. (2014) · ACS Catalysis · doi:10.1021/cs500143j · Cited by 131

The Impact of Specifically Adsorbed Ions on the Copper-Catalyzed Electroreduction of CO2

Akhade, S. A., McCrum, I. T., & Janik, M. J. (2016) · Journal of The Electrochemical Society · doi:10.1149/2.0581606jes · Cited by 120

Selective reduction of CO 2 to formate through bicarbonate reduction on metal electrodes: new insights gained from SG/TC mode of SECM

Narayanaru, S., & Phani, K. L. N. (2014) · Chemical Communications · doi:10.1039/c4cc03099k · Cited by 117

Theory of the transition from sequential to concerted electrochemical proton–electron transfer

Koper, M. T. M. (2012) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp42369c · Cited by 116

Reaction intermediates during operando electrocatalysis identified from full solvent quantum mechanics molecular dynamics

Cheng, T., Fortunelli, A., & Goddard, W. A. (2019) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1821709116 · Cited by 115

Role of the Adsorbed Oxygen Species in the Selective Electrochemical Reduction of CO 2 to Alcohols and Carbonyls on Copper Electrodes

Duff, C. S. L., Lawrence, M. J., & Rodríguez, P. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201706463 · Cited by 111

Importance of Solvation for the Accurate Prediction of Oxygen Reduction Activities of Pt-Based Electrocatalysts

He, Z., Hanselman, S., Chen, Y., Koper, M. T. M., & Calle‐Vallejo, F. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b01018 · Cited by 110

Tailoring Metal-Porphyrin-Like Active Sites on Graphene to Improve the Efficiency and Selectivity of Electrochemical CO2 Reduction

Cheng, M., Kwon, Y., Head‐Gordon, M., & Bell, A. T. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b05518 · Cited by 108

FTIR spectroscopy study of the reduction of carbon dioxide on lead electrode in aqueous medium

Innocent, B., Pasquier, D., Ropital, F., Hahn, F., ́GER, J.-M. L., & Kokoh, K. B. (2009) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2009.10.027 · Cited by 106

A brief review of the computational modeling of CO2 electroreduction on Cu electrodes

Rendón-Calle, A., Builes, S., & Calle‐Vallejo, F. (2018) · Current Opinion in Electrochemistry · doi:10.1016/j.coelec.2018.03.012 · Cited by 104

Renewable Formate from C–H Bond Formation with CO2: Using Iron Carbonyl Clusters as Electrocatalysts

Loewen, N. D., Neelakantan, T. V., & Berben, L. A. (2017) · Accounts of Chemical Research · doi:10.1021/acs.accounts.7b00302 · Cited by 100

Determinant Role of Electrogenerated Reactive Nucleophilic Species on Selectivity during Reduction of CO2 Catalyzed by Metalloporphyrins

Göttle, A. J., & Koper, M. T. M. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b11267 · Cited by 98

Role of Subsurface Oxygen on Cu Surfaces for CO2 Electrochemical Reduction

Fields, M., Hong, X., Nørskov, J. K., & Chan, K. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b04983 · Cited by 97

Solvent–Adsorbate Interactions and Adsorbate-Specific Solvent Structure in Carbon Dioxide Reduction on a Stepped Cu Surface

Ludwig, T., Gauthier, J. A., Brown, K. S., Ringe, S., Nørskov, J. K., & Chan, K. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b11571 · Cited by 94

Influence of the metal center of metalloprotoporphyrins on the electrocatalytic CO2 reduction to formic acid

Birdja, Y. Y., Shen, J., & Koper, M. T. M. (2017) · Catalysis Today · doi:10.1016/j.cattod.2017.02.046 · Cited by 92

Accounting for Bifurcating Pathways in the Screening for CO2 Reduction Catalysts

Calle‐Vallejo, F., & Koper, M. T. M. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b02917 · Cited by 90

Morphology-controlled CuO nanoparticles for electroreduction of CO 2 to ethanol

Chi, D., Yang, H., Du, Y., Lv, T., Sui, G.-J., Wang, H., & Lu, J. (2014) · RSC Advances · doi:10.1039/c4ra05415f · Cited by 84

Effects of mass transfer on the electrocatalytic CO 2 reduction on Cu

Lim, C. F. C., Harrington, D. A., & Marshall, A. T. (2017) · Electrochimica Acta · doi:10.1016/j.electacta.2017.04.017 · Cited by 83

New insights into working nanostructured electrocatalysts through operando spectroscopy and microscopy

Choi, Y., Mistry, H., & Cuenya, B. R. (2017) · Current Opinion in Electrochemistry · doi:10.1016/j.coelec.2017.01.004 · Cited by 73

Activity volcanoes for the electrocatalysis of homolytic and heterolytic hydrogen evolution

Koper, M. T. M. (2015) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-015-3036-z · Cited by 64

Theoretical insight on reactivity trends in CO 2 electroreduction across transition metals

Akhade, S. A., Luo, W., Nie, X., Asthagiri, A., & Janik, M. J. (2015) · Catalysis Science & Technology · doi:10.1039/c5cy01339a · Cited by 62

2D Covalent Metals: A New Materials Domain of Electrochemical CO2 Conversion with Broken Scaling Relationship

Shin, H., Ha, Y., & Kim, H. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b01876 · Cited by 61

Thermodynamic assessment of the oxygen reduction activity in aqueous solutions

Tripković, V. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp05448c · Cited by 55

Computational investigation of CO 2 electroreduction on tin oxide and predictions of Ti, V, Nb and Zr dopants for improved catalysis

Saravanan, K., Basdogan, Y., Dean, J., & Keith, J. A. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta00405b · Cited by 46

CO 2 reduction at low overpotential on Cu electrodes in the presence of impurities at the subsurface

Xiao, J., Kuc, A. B., Frauenheim, T., & Heine, T. (2014) · Journal of Materials Chemistry A · doi:10.1039/c3ta14755j · Cited by 38

Organic reactions for the electrochemical and photochemical production of chemical fuels from CO2 – The reduction chemistry of carboxylic acids and derivatives as bent CO2 surrogates

Luca, O. R., & Fenwick, A. Q. (2015) · Journal of Photochemistry and Photobiology B Biology · doi:10.1016/j.jphotobiol.2015.04.015 · Cited by 32

Nitrogen-doped nanocarbon materials under electroreduction operating conditions and implications for electrocatalysis of CO2

Saravanan, K., Gottlieb, E. R., & Keith, J. A. (2016) · Carbon · doi:10.1016/j.carbon.2016.10.084 · Cited by 24

Quantum Chemical Analyses of BH4− and BH3OH− Hydride Transfers to CO2 in Aqueous Solution with Potentials of Mean Force

Groenenboom, M. C., & Keith, J. A. (2017) · ChemPhysChem · doi:10.1002/cphc.201700608 · Cited by 9

Technologies and perspectives for achieving carbon neutrality

Wang, F., Harindintwali, J. D., Yuan, Z., Wang, M., Wang, F., Li, S., Yin, Z., Huang, L., Fu, Y., Li, L., et al. (2021) · The Innovation · doi:10.1016/j.xinn.2021.100180 · Cited by 1,330

Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution

Monteiro, M. C. O., Dattila, F., Hagedoorn, B. J. L., García‐Muelas, R., López, N., & Koper, M. T. M. (2021) · Nature Catalysis · doi:10.1038/s41929-021-00655-5 · Cited by 1,040

Advances and Challenges for the Electrochemical Reduction of CO 2 to CO: From Fundamentals to Industrialization

Jin, S., Hao, Z., Zhang, K., Yan, Z., & Chen, J. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202101818 · Cited by 1,039

Advanced Electrocatalysts with Single-Metal-Atom Active Sites

Wang, Y., Su, H., He, Y., Li, L., Zhu, S., Shen, H. F., Xie, P., Fu, X., Zhou, G., Feng, C., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00594 · Cited by 1,009

Transition metal nitrides for electrochemical energy applications

Wang, H., Li, J., Li, K., Lin, Y., Chen, J., Gao, L., Nicolosi, V., Xiao, X., & Lee, J.-M. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00415d · Cited by 983

Photocatalytic CO2 reduction

Fang, S., Rahaman, M., Bharti, J., Reisner, E., Robert, M., Ozin, G. A., & Hu, Y. H. (2023) · Nature Reviews Methods Primers · doi:10.1038/s43586-023-00243-w · Cited by 883

Operando studies reveal active Cu nanograins for CO2 electroreduction

Yang, Y., Louisia, S., Yu, S., Jin, J., Roh, I., Chen, C., Guzman, M. V. F., Feijóo, J., Chen, P., Wang, H., et al. (2023) · Nature · doi:10.1038/s41586-022-05540-0 · Cited by 863

Power-to-liquid via synthesis of methanol, DME or Fischer–Tropsch-fuels: a review

Dieterich, V., Buttler, A., Hanel, A., Spliethoff, H., & Fendt, S. (2020) · Energy & Environmental Science · doi:10.1039/d0ee01187h · Cited by 828

Proton-Coupled Electron Transfer Guidelines, Fair and Square

Tyburski, R., Liu, T., Glover, S. D., & Hammarström, L. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.0c09106 · Cited by 739

Towards molecular understanding of local chemical environment effects in electro- and photocatalytic CO2 reduction

Wagner, A., Sahm, C. D., & Reisner, E. (2020) · Nature Catalysis · doi:10.1038/s41929-020-00512-x · Cited by 768

Noble-Metal Nanocrystals with Controlled Shapes for Catalytic and Electrocatalytic Applications

Shi, Y., Lyu, Z., Zhao, M., Chen, R., Nguyen, Q. N., & Younan Xia, A. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00454 · Cited by 736

Cooperative CO2-to-ethanol conversion via enriched intermediates at molecule–metal catalyst interfaces

Li, F., Li, Y., Wang, Z., Li, J., Nam, D., Lum, Y., Luo, M., Wang, X., Ozden, A., Hung, S., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0383-7 · Cited by 764

Electrocatalytic Refinery for Sustainable Production of Fuels and Chemicals

Tang, C., Zheng, Y., Jaroniec, M., & Qiao, S. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202101522 · Cited by 729

Electrocatalytic reduction of CO 2 and CO to multi-carbon compounds over Cu-based catalysts

Ma, W., He, X., Wang, W., Xie, S., Zhang, Q., & Wang, Y. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00535a · Cited by 723

Protecting Copper Oxidation State via Intermediate Confinement for Selective CO 2 Electroreduction to C 2+ Fuels

Yang, P., Zhang, X., Gao, F., Zheng, Y., Niu, Z., Yu, X., Liu, R., Wu, Z., Qin, S., Chi, L., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c01699 · Cited by 714

Lattice oxygen redox chemistry in solid-state electrocatalysts for water oxidation

Zhang, N., & Chai, Y. (2021) · Energy & Environmental Science · doi:10.1039/d1ee01277k · Cited by 713

Copper-catalysed exclusive CO2 to pure formic acid conversion via single-atom alloying

Zheng, T., Liu, C., Guo, C., Zhang, M., Xu, L., Jiang, Q. M., Xue, W., Li, H., Li, A., Pao, C., et al. (2021) · Nature Nanotechnology · doi:10.1038/s41565-021-00974-5 · Cited by 725

Heterogeneous Single‐Atom Catalysts for Electrochemical CO2 Reduction Reaction

Li, M., Wang, H., Luo, W. D., Sherrell, P. C., Chen, J., & Yang, J. (2020) · Advanced Materials · doi:10.1002/adma.202001848 · Cited by 695

Defect Engineering in Carbon‐Based Electrocatalysts: Insight into Intrinsic Carbon Defects

Zhu, J., & Mu, S. C. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202001097 · Cited by 682

Gas diffusion electrodes and membranes for CO2 reduction electrolysers

Lees, E. W., Mowbray, B. A. W., Parlane, F. G. L., & Berlinguette, C. P. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00356-2 · Cited by 711

Highlights and challenges in the selective reduction of carbon dioxide to methanol

Navarro‐Jaén, S., Virginie, M., Bonin, J., Robert, M., Wojcieszak, R., & Khodakov, A. Y. (2021) · Nature Reviews Chemistry · doi:10.1038/s41570-021-00289-y · Cited by 670

Competition between CO2 Reduction and Hydrogen Evolution on a Gold Electrode under Well-Defined Mass Transport Conditions

Goyal, A., Marcandalli, G., Mints, V. A., & Koper, M. T. M. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b10061 · Cited by 661

Cell-free chemoenzymatic starch synthesis from carbon dioxide

Cai, T., Sun, H., Qiao, J., Zhu, L., Zhang, F., Zhang, J., Tang, Z., Wei, X., Yang, J., Yuan, Q., et al. (2021) · Science · doi:10.1126/science.abh4049 · Cited by 640

The Sabatier Principle in Electrocatalysis: Basics, Limitations, and Extensions

Ooka, H., Huang, J., & Exner, K. S. (2021) · Frontiers in Energy Research · doi:10.3389/fenrg.2021.654460 · Cited by 634

Mechanistic Understanding of CO 2 Reduction Reaction (CO2RR) Toward Multicarbon Products by Heterogeneous Copper-Based Catalysts

Todorova, T. K., Schreiber, M. W., & Fontecave, M. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b04746 · Cited by 602

Boosting electrocatalytic CO2–to–ethanol production via asymmetric C–C coupling

Wang, P., Yang, H., Tang, C., Wu, Y. S., Zheng, Y., Cheng, T., Davey, K. R., Huang, X., & Qiao, S. (2022) · Nature Communications · doi:10.1038/s41467-022-31427-9 · Cited by 626

Electrochemical CO2 reduction (CO2RR) to multi-carbon products over copper-based catalysts

Woldu, A. R., Huang, Z., Zhao, P., Hu, L., & Astruc, D. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.214340 · Cited by 587

Revealing the CO Coverage-Driven C–C Coupling Mechanism for Electrochemical CO 2 Reduction on Cu 2 O Nanocubes via Operando Raman Spectroscopy

Zhan, C., Dattila, F., Rettenmaier, C., Bergmann, A., Kühl, S., García‐Muelas, R., López, N., & Cuenya, B. R. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c01478 · Cited by 566

Transition metal-based catalysts for the electrochemical CO 2 reduction: from atoms and molecules to nanostructured materials

Franco, F., Rettenmaier, C., Jeon, H. S., & Cuenya, B. R. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00835d · Cited by 552

High-entropy alloys in electrocatalysis: from fundamentals to applications

Ren, J.-T., Chen, L., Wang, H.-Y., & Yuan, Z.-Y. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00557g · Cited by 551

Electrochemical oxidation of biomass derived 5-hydroxymethylfurfural (HMF): pathway, mechanism, catalysts and coupling reactions

Yang, Y., & Mu, T. (2021) · Green Chemistry · doi:10.1039/d1gc00914a · Cited by 539

Gas diffusion electrodes (GDEs) for electrochemical reduction of carbon dioxide, carbon monoxide, and dinitrogen to value-added products: a review

Rabiee, H., Ge, L., Zhang, X., Hu, S., Li, M., & Yuan, Z. (2021) · Energy & Environmental Science · doi:10.1039/d0ee03756g · Cited by 519

Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide

Liang, Z., Wang, H., Zheng, H., Zhang, W., & Cao, R. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01482f · Cited by 512

Comprehensive Understanding of the Thriving Ambient Electrochemical Nitrogen Reduction Reaction

Zhao, X., Hu, G., Chen, G., Zhang, H., Zhang, S., & Wang, H. (2021) · Advanced Materials · doi:10.1002/adma.202007650 · Cited by 504

Strain enhances the activity of molecular electrocatalysts via carbon nanotube supports

Su, J., Musgrave, C. B., Song, Y. M., Huang, L., Liu, Y., Li, G., Xin, Y., Xiong, P., Li, M. M., Wu, H., et al. (2023) · Nature Catalysis · doi:10.1038/s41929-023-01005-3 · Cited by 500

Electrocatalytic CO 2 -to-C 2+ with Ampere-Level Current on Heteroatom-Engineered Copper via Tuning *CO Intermediate Coverage

Zheng, M. J., Wang, P., Zhi, X., Yang, K., Jiao, Y., Duan, J., Zheng, Y., & Qiao, S. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c06820 · Cited by 475

Green Carbon Science: Efficient Carbon Resource Processing, Utilization, and Recycling towards Carbon Neutrality

He, M., Sun, Y., & Han, B. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202112835 · Cited by 470

Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts

Sun, L., Reddu, V., Fisher, A. C., & Wang, X. (2019) · Energy & Environmental Science · doi:10.1039/c9ee03660a · Cited by 463

Efficient electron transmission in covalent organic framework nanosheets for highly active electrocatalytic carbon dioxide reduction

Zhu, H., Lu, M., Wang, Y., Yao, S., Zhang, M., Kan, Y., Liu, J., Chen, Y., Li, S., & Lan, Y. (2020) · Nature Communications · doi:10.1038/s41467-019-14237-4 · Cited by 460

Designing CO 2 reduction electrode materials by morphology and interface engineering

Pan, F., & Yang, Y. (2020) · Energy & Environmental Science · doi:10.1039/d0ee00900h · Cited by 446

Modulating Local CO2 Concentration as a General Strategy for Enhancing C−C Coupling in CO2 Electroreduction

Tan, Y. C., Lee, K. B., Song, H., & Oh, J. (2020) · Joule · doi:10.1016/j.joule.2020.03.013 · Cited by 443

The Role of Cation Acidity on the Competition between Hydrogen Evolution and CO 2 Reduction on Gold Electrodes

Monteiro, M. C. O., Dattila, F., López, N., & Koper, M. T. M. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c10171 · Cited by 421

Atypical Oxygen-Bearing Copper Boosts Ethylene Selectivity toward Electrocatalytic CO 2 Reduction

Zhang, W., Huang, C., Xiao, Q., Yu, L., Shuai, L., An, P., Zhang, J., Qiu, M., Ren, Z., & Yu, Y. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c01562 · Cited by 414

Recent Advances in MOF‐Derived Single Atom Catalysts for Electrochemical Applications

Song, Z., Zhang, L., Doyle‐Davis, K., Fu, X., Luo, J., & Sun, X. A. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001561 · Cited by 414

Dynamically Formed Surfactant Assembly at the Electrified Electrode–Electrolyte Interface Boosting CO2 Electroreduction

Ge, W., Chen, Y., Yu, F., Zhu, Y., Liu, H., Song, L., Liu, Z., Lian, C., Jiang, H., & Li, C. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c02486 · Cited by 411

Gas diffusion electrode design for electrochemical carbon dioxide reduction

Nguyen, T. N., & Dinh, C. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00230e · Cited by 406

Local reaction environment in electrocatalysis

Chen, C., Jin, H., Wang, P., Sun, X., Jaroniec, M., Zheng, Y., & Qiao, S. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00669g · Cited by 401

Unified mechanistic understanding of CO2 reduction to CO on transition metal and single atom catalysts

Vijay, S., Ju, W., Brückner, S., Tsang, S., Strasser, P., & Chan, K. (2021) · Nature Catalysis · doi:10.1038/s41929-021-00705-y · Cited by 399

Efficient Electrocatalytic CO2 Reduction to C2+ Alcohols at Defect-Site-Rich Cu Surface

Gu, Z., Shen, H. F., Chen, Z., Yang, Y., Yang, C., Ji, Y., Wang, Y., Zhu, C., Liu, J., Li, J., et al. (2021) · Joule · doi:10.1016/j.joule.2020.12.011 · Cited by 402

Metal–Organic Framework‐Derived Carbon Nanorods Encapsulating Bismuth Oxides for Rapid and Selective CO 2 Electroreduction to Formate

Deng, P., Yang, F., Wang, Z., Chen, S., Zhou, Y., Zaman, S., & Xia, B. Y. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202000657 · Cited by 395

Recent advances in electrocatalysis with phthalocyanines

Yang, S., Yu, Y., Gao, X., Zhang, Z., & Wang, F. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01605e · Cited by 395

Recent advances in innovative strategies for the CO 2 electroreduction reaction

Tan, X., Yu, C., Ren, Y., Cui, S., Li, W., & Qiu, J. (2020) · Energy & Environmental Science · doi:10.1039/d0ee02981e · Cited by 386

Key intermediates and Cu active sites for CO2 electroreduction to ethylene and ethanol

Zhan, C., Dattila, F., Rettenmaier, C., Herzog, A., Herran, M., Wagner, T., Scholten, F., Bergmann, A., López, N., & Cuenya, B. R. (2024) · Nature Energy · doi:10.1038/s41560-024-01633-4 · Cited by 383

Design strategies for markedly enhancing energy efficiency in the electrocatalytic CO 2 reduction reaction

Lai, W., Qiao, Y., Zhang, J., Lin, Z., & Huang, H. (2022) · Energy & Environmental Science · doi:10.1039/d2ee00472k · Cited by 381

Morphology and mechanism of highly selective Cu(II) oxide nanosheet catalysts for carbon dioxide electroreduction

Wang, X., Klingan, K., Klingenhof, M., Möller, T., de Araujo, J. V. F., Martens, I., Bagger, A., Jiang, S. H., Rossmeisl, J., Dau, H., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-20961-7 · Cited by 383

Accelerating electrochemical CO2 reduction to multi-carbon products via asymmetric intermediate binding at confined nanointerfaces

Zhang, J., Guo, C., Fang, S., Zhao, X., Li, L., Jiang, H., Liu, Z., Fan, Z., Xu, W., Xiao, J., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-36926-x · Cited by 406

Operando cathode activation with alkali metal cations for high current density operation of water-fed zero-gap carbon dioxide electrolysers

Endrődi, B., Samu, A. A., Kecsenovity, E., Halmagyi, T. G., Sebők, D., & Janáky, C. (2021) · Nature Energy · doi:10.1038/s41560-021-00813-w · Cited by 390

Architectural Design for Enhanced C 2 Product Selectivity in Electrochemical CO 2 Reduction Using Cu-Based Catalysts: A Review

Xiao, C., & Zhang, J. (2021) · ACS Nano · doi:10.1021/acsnano.0c10697 · Cited by 373

Room-temperature photosynthesis of propane from CO2 with Cu single atoms on vacancy-rich TiO2

Shen, Y., Ren, C., Zheng, L., Xu, X., Long, R., Zhang, W., Yang, Y., Zhang, Y., Yao, Y., Chi, H., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-36778-5 · Cited by 363

Double sulfur vacancies by lithium tuning enhance CO2 electroreduction to n-propanol

Chen, P., Luo, G., Zhang, J., Chen, M., Wang, Z., Sham, T., Zhang, L., Li, Y., & Zheng, G. (2021) · Nature Communications · doi:10.1038/s41467-021-21901-1 · Cited by 366

Transforming carbon dioxide into jet fuel using an organic combustion-synthesized Fe-Mn-K catalyst

Yao, B., Xiao, T., Makgae, O. A., Jie, X. M., González-Cortés, S. L., Guan, S., Kirkland, A. I., Dilworth, J. R., Al‐Megren, H. A., Alshihri, S. M., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-20214-z · Cited by 360

Silver Single‐Atom Catalyst for Efficient Electrochemical CO2 Reduction Synthesized from Thermal Transformation and Surface Reconstruction

Zhang, N., Zhang, X., Tao, L., Jiang, P., Ye, C., Lin, R., Huang, Z., Li, A., Pang, D., Yan, H., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202014718 · Cited by 359

High-Density Cobalt Single-Atom Catalysts for Enhanced Oxygen Evolution Reaction

Kumar, P., Karthick, K., Zeraati, A. S., Roy, S., Wang, X., Wang, X., Samanta, S., Miller, K. A., Molina, M., Trivedi, D., et al. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c00537 · Cited by 359

Sub‐Second Time‐Resolved Surface‐Enhanced Raman Spectroscopy Reveals Dynamic CO Intermediates during Electrochemical CO 2 Reduction on Copper

An, H., Wu, L., Mandemaker, L. D. B., Yang, S., de Ruiter, J., Wijten, J. H. J., Janssens, J. C. L., Hartman, T., van der Stam, W., & Weckhuysen, B. M. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202104114 · Cited by 359

Suppression of Hydrogen Evolution in Acidic Electrolytes by Electrochemical CO2 Reduction

Bondue, C. J., Graf, M., Goyal, A., & Koper, M. T. M. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c10397 · Cited by 357

Enrichment of reactants and intermediates for electrocatalytic CO 2 reduction

Yang, P., & Gao, M. (2023) · Chemical Society Reviews · doi:10.1039/d2cs00849a · Cited by 361

Designing Copper‐Based Catalysts for Efficient Carbon Dioxide Electroreduction

Wang, Y., Liu, J., & Zheng, G. (2021) · Advanced Materials · doi:10.1002/adma.202005798 · Cited by 353

Accelerating CO 2 Electroreduction to Multicarbon Products via Synergistic Electric–Thermal Field on Copper Nanoneedles

Yang, B., Liu, K., Li, H., Liu, C., Fu, J., Li, H., Huang, J. E., Ou, P., Alkayyali, T., Cai, C., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c11253 · Cited by 346

High‐Rate CO2 Electroreduction to C2+ Products over a Copper‐Copper Iodide Catalyst

Li, H., Liu, T., Wei, P., Lin, L., Gao, D., Wang, G., & Bao, X. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202102657 · Cited by 345

Electroreduction of CO 2 : Advances in the Continuous Production of Formic Acid and Formate

Fernández-Caso, K., Díaz‐Sainz, G., Álvarez-Guerra, M., & Irabien, Á. (2023) · ACS Energy Letters · doi:10.1021/acsenergylett.3c00489 · Cited by 347

Electronic Modulation of Non‐van der Waals 2D Electrocatalysts for Efficient Energy Conversion

Wang, H., Chen, J., Lin, Y., Wang, X., Li, J., Li, Y., Gao, L., Zhang, L., Chao, D., Xiao, X. R., et al. (2021) · Advanced Materials · doi:10.1002/adma.202008422 · Cited by 344

Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions

Amirbeigiarab, R., Tian, J., Herzog, A., Qiu, C., Bergmann, A., Cuenya, B. R., & Magnussen, O. M. (2023) · Nature Catalysis · doi:10.1038/s41929-023-01009-z · Cited by 344

The nature of active sites for carbon dioxide electroreduction over oxide-derived copper catalysts

Cheng, D., Zhao, Z., Zhang, G., Yang, P., Li, L., Gao, H., Liu, S., Chang, X., Chen, S., Wang, T., et al. (2021) · Nature Communications · doi:10.1038/s41467-020-20615-0 · Cited by 340

Molecular Views on Fischer–Tropsch Synthesis

Rommens, K. T., & Saeys, M. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00508 · Cited by 339

Interfacial Electrolyte Effects on Electrocatalytic CO2 Reduction

Deng, B., Huang, M. Y., Zhao, X., Mou, S., & Dong, F. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c03501 · Cited by 337

p–d Orbital Hybridization Induced by p-Block Metal-Doped Cu Promotes the Formation of C 2+ Products in Ampere-Level CO 2 Electroreduction

Li, P., Bi, J., Liu, J., Wang, Y., Kang, X., Sun, X., Zhang, J., Liu, Z., Zhu, Q., & Han, B. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.2c12743 · Cited by 332

Multiscale CO 2 Electrocatalysis to C 2+ Products: Reaction Mechanisms, Catalyst Design, and Device Fabrication

Yan, T., Chen, X., Kumari, L., Lin, J., Li, M., Fan, Q., Chi, H., Meyer, T. J., Zhang, S., & Ma, X. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00514 · Cited by 337

Potential Link between Cu Surface and Selective CO2 Electroreduction: Perspective on Future Electrocatalyst Designs

Tomboc, G. M., Choi, S., Kwon, T., Hwang, Y. J., & Lee, K. (2020) · Advanced Materials · doi:10.1002/adma.201908398 · Cited by 329

Linking the Dynamic Chemical State of Catalysts with the Product Profile of Electrocatalytic CO 2 Reduction

Wang, J., Tan, H., Zhu, Y., Chu, H., & Chen, H. M. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202017181 · Cited by 325

Efficient multicarbon formation in acidic CO2 reduction via tandem electrocatalysis

Chen, Y., Li, X., Chen, Z., Ozden, A., Huang, J. E., Ou, P., Dong, J., Zhang, J., Tian, C., Lee, B., et al. (2023) · Nature Nanotechnology · doi:10.1038/s41565-023-01543-8 · Cited by 325

Electrocatalytic nitrate reduction to ammonia on defective Au1Cu (111) single-atom alloys

Zhang, Y., Chen, X., Wang, W., Yin, L., & Crittenden, J. C. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.121346 · Cited by 322

Recent Progresses in Electrochemical Carbon Dioxide Reduction on Copper‐Based Catalysts toward Multicarbon Products

Yu, J., Wang, J., Ma, Y., Zhou, J., Wang, Y., Lu, P., Yin, J., Ye, R., Zhu, Z., & Fan, Z. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202102151 · Cited by 317

Bi‐Based Metal‐Organic Framework Derived Leafy Bismuth Nanosheets for Carbon Dioxide Electroreduction

Yang, J., Wang, X., Qu, Y., Wang, X., Huo, H., Fan, Q., Wang, J., Yang, L., & Wu, Y. S. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001709 · Cited by 314

Tuning metal single atoms embedded in N x C y moieties toward high-performance electrocatalysis

Ha, M., Kim, D. Y., Umer, M., Gladkikh, V., Myung, C. W., & Kim, K. S. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00154j · Cited by 308

Synergistic Effect of Atomically Dispersed Ni–Zn Pair Sites for Enhanced CO 2 Electroreduction

Li, Y., Wei, B., Zhu, M., Chen, J., Jiang, Q., Yang, B., Hou, Y., Lei, L., Li, Z., Zhang, R., et al. (2021) · Advanced Materials · doi:10.1002/adma.202102212 · Cited by 311

Regulating the coordination structure of metal single atoms for efficient electrocatalytic CO 2 reduction

Wang, Y., Liu, Y., Liu, W., Wu, J., Li, Q., Feng, Q., Chen, Z., Xiong, X., Wang, D. S., & Lei, Y. (2020) · Energy & Environmental Science · doi:10.1039/d0ee02833a · Cited by 306

The reformation of catalyst: From a trial-and-error synthesis to rational design

Wang, L., Wu, J., Wang, S., Liu, H., Wang, Y., & Wang, D. S. (2023) · Nano Research · doi:10.1007/s12274-023-6037-8 · Cited by 312

Elucidating electrochemical CO 2 reduction reaction processes on Cu( hkl ) single-crystal surfaces by in situ Raman spectroscopy

Zhao, Y., Zhang, X., Bodappa, N., Yang, W., Liang, Q. Y., Radjenovic, P. M., Wang, Y., Zhang, Y., Dong, J., Tian, Z., et al. (2022) · Energy & Environmental Science · doi:10.1039/d2ee01334g · Cited by 298

Current progress in electrocatalytic carbon dioxide reduction to fuels on heterogeneous catalysts

Liu, A., Gao, M., Ren, X., Meng, F., Yang, Y., Gao, L., Yang, Q., & Ma, T. (2020) · Journal of Materials Chemistry A · doi:10.1039/c9ta11966c · Cited by 295

Nano-crumples induced Sn-Bi bimetallic interface pattern with moderate electron bank for highly efficient CO2 electroreduction

Ren, B., Wen, G., Gao, R., Luo, D., Zhang, Z., Qiu, W., Ma, Q., Wang, X., Cui, Y., Ricardez‐Sandoval, L., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-29861-w · Cited by 310

Ethylene Selectivity in Electrocatalytic CO2 Reduction on Cu Nanomaterials: A Crystal Phase-Dependent Study

Chen, Y., Fan, Z., Wang, J., Ling, C., Niu, W., Huang, Z., Liu, G., Chen, B., Lai, Z., Liu, X., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c04981 · Cited by 292

Enhanced Cuprophilic Interactions in Crystalline Catalysts Facilitate the Highly Selective Electroreduction of CO 2 to CH 4

Zhang, L., Li, X., Lang, Z., Liu, Y., Liu, J., Yuan, L., Lu, W., Xia, Y., Dong, L., Yuan, D., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.0c11450 · Cited by 289

Halide-guided active site exposure in bismuth electrocatalysts for selective CO2 conversion into formic acid

Yang, S., An, H., Arnouts, S., Wang, H., Yu, X., de Ruiter, J., Bals, S., Altantzis, T., Weckhuysen, B. M., & van der Stam, W. (2023) · Nature Catalysis · doi:10.1038/s41929-023-01008-0 · Cited by 287

Long-chain hydrocarbons by CO2 electroreduction using polarized nickel catalysts

Zhou, Y., Martín, A. J., Dattila, F., Xi, S., López, N., Pérez‐Ramírez, J., & Yeo, B. S. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00803-5 · Cited by 291

Coverage-driven selectivity switch from ethylene to acetate in high-rate CO2/CO electrolysis

Wei, P., Gao, D., Liu, T., Li, H., Sang, J., Wang, C., Cai, R., Wang, G., & Bao, X. (2023) · Nature Nanotechnology · doi:10.1038/s41565-022-01286-y · Cited by 290

Advances and Challenges for the Electrochemical Reduction of CO 2 to CO: From Fundamentals to Industrialization

Jin, S., Hao, Z., Zhang, K., Yan, Z., & Chen, J. (2021) · Angewandte Chemie · doi:10.1002/ange.202101818 · Cited by 271

Confined Growth of Silver–Copper Janus Nanostructures with {100} Facets for Highly Selective Tandem Electrocatalytic Carbon Dioxide Reduction

Ma, Y., Yu, J., Sun, M., Chen, B., Zhou, X., Ye, C., Guan, Z., Guo, W., Wang, G., Lu, S., et al. (2022) · Advanced Materials · doi:10.1002/adma.202110607 · Cited by 275

Recent advancements in metal oxides for energy storage materials: Design, classification, and electrodes configuration of supercapacitor

Shaheen, I., Hussain, I., Zahra, T., Javed, M. S., Shah, S. S. A., Khan, K., Hanif, M. B., Assiri, M. A., Said, Z., Arifeen, W. U., et al. (2023) · Journal of Energy Storage · doi:10.1016/j.est.2023.108719 · Cited by 269

Tricycloquinazoline‐Based 2D Conductive Metal–Organic Frameworks as Promising Electrocatalysts for CO2Reduction

Liu, J., Yang, D., Zhou, Y., Zhang, G., Xing, G., Liu, Y., Ma, Y., Terasaki, O., Yang, S., & Chen, L. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202103398 · Cited by 268

Opportunities of Aqueous Manganese‐Based Batteries with Deposition and Stripping Chemistry

Wang, M., Zheng, X., Zhang, X., Chao, D., Qiao, S., Alshareef, H. N., Cui, Y., & Chen, W. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202002904 · Cited by 265

Recent advances in understanding mechanisms for the electrochemical reduction of carbon dioxide

Ting, L. R. L., & Yeo, B. S. (2018) · Current Opinion in Electrochemistry · doi:10.1016/j.coelec.2018.04.011 · Cited by 104

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990

Electrochemical CO2 reduction: Electrocatalyst, reaction mechanism, and process engineering

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