Construction and Operating Mechanism of High‐Rate Mo‐Doped Na3V2(PO4)3@C Nanowires toward Practicable Wide‐Temperature‐Tolerance Na‐Ion and Hybrid Li/Na‐Ion Batteries
Abstract
The growing demand for cost‐efficiency and safe energy storage systems has stimulated enormous interest worldwide in advanced cathodes for practicle “beyond‐Li‐ion” batteries. Herein, a feasible electrospinning/annealing avenue for the construction of 1D Mo‐doped Na 3 V 2(PO 4)3 nanowires in situ coated with carbon nanoshell (MNVP@C NWs) toward next‐generation Na‐ion batteries (NIBs) and hybrid Li/Na‐ion batteries (HLNIBs) as a high‐rate cathode material, is reported. Particularly, the intrinsic hybrid Li/Na‐ion storage mechanism of the MNVP@C NWs is unveiled for the HLNIBs with comprehensive characterizations. The resultant MNVP@C NWs demonstrate rapid electronic/ionic transport and rigid structural tolerance within operating temperatures from ‐25 to 55 °C, benefiting from its unique structural/compositional merits. More competitively, the MNVP@C NWs assembled pouch‐type NIBs (‐15 to 25 °C) and HLNIBs (‐25 to 55 °C) both exhibit remarkable wide‐temperature‐tolerance electrochemical properties in terms of high‐rate capabilities and long‐duration cycling lifespan, along with material‐level energy densities of ≈262.4 and ≈186.1 Wh kg‐1 at 25 °C, respectively. The contribution here is expected to exert a stimulative impact upon the future design of versatile cathodes for advanced high energy/power rechargeable batteries.
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Liang et al. synthesized Mo-doped NVP/C in pouch-type full cells with commercial Li4Ti5O12 (LTO), maintained approximately 72.5% of room-temperature capacity at −25 °C.
“Liang et al. synthesized Mo-doped NVP/C in pouch-type full cells with commercial Li4Ti5O12 (LTO), maintained approximately 72.5% of RT capacity at −25 °C21.”
From High-performance Na3V2(PO4)3/C cathode for efficient low-temperature lithium-ion batteries (2025) · cites this paper as [21]
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High-performance Na3V2(PO4)3/C cathode for efficient low-temperature lithium-ion batteries
Mukushev, I., Tyan, Y., Kalimuldina, G., Mukanova, A., Jakupova, Z., Kim, S.-S., Bakenov, Z., & Nurpeissova, A. (2025) · NPG Asia Materials · doi:10.1038/s41427-025-00591-x · Cited by 11 · see citing works
“Liang et al. synthesized Mo-doped NVP/C in pouch-type full cells with commercial Li4Ti5O12 (LTO), maintained approximately 72.5% of RT capacity at − 25 °C 21 .”
Influential
- Authors
- Liang, L., Li, X., Zhao, F., Zhang, J., Liu, Y., Hou, L., & Yuan, C.
- Affiliations
- University of Jinan (CN)
- Corresponding author
- Yuan, Changzhou
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2021-03-31
- Volume
- 11
- Issue
- 21
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W3147912559
- Cited by
- 150
- References
- 0
- Citations by year
- 2026: 16 · 2025: 21 · 2024: 35 · 2023: 39 · 2022: 25 · 2021: 14
- FWCI
- 8.31
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Energy Materials (publishedVersion)
- Funders
- National Natural Science Foundation of China (51772127, 51772131, 51904115, 52072151)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Keywords
- Na3V2(PO4)3, molybdenum doping, nanowires, electrospinning, cathode materials, sodium-ion batteries, rate capability, pouch-type battery, energy density
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