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Effect of the product layer on the kinetics of the CO2‐lime reaction
Abstract
The kinetics of reaction between CO 2 and lime is investigated in the range of 673 to 998 K with a view to examining the effects of product layer deposition and variations in the limestone calcination atmosphere. The reaction is initially rapid and chemically controlled and goes through a sudden transition to a much slower regime controlled by diffusion in the product CaCO 3 layer. The magnitude of the estimated product layer diffusivity is in the range of 10−18 to 10−21 m 2/s, the corresponding activation energy is 88.9 ± 3.7 kJ/mol below 688 K and 179.2 ± 7.0 kJ/mol above that temperature, suggestive of solid state diffusion. Plausible mechanisms are discussed.
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Citations
Cites
Self-diffusion of carbon and oxygen in calcite by isotope exchange with carbon dioxide
Anderson, T. F. (1969) · Journal of Geophysical Research · doi:10.1029/jb074i015p03918 · Cited by 123
Cited by
CO2 capture by solid adsorbents and their applications: current status and new trends
Wang, Q., Luo, J., Zhong, Z., & Borgna, A. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00064g · Cited by 1,611
Carbon dioxide disposal in carbonate minerals
Lackner, K. S., Wendt, C. H., Butt, D. P., Joyce, E. L., & Sharp, D. H. (1995) · Energy · doi:10.1016/0360-5442(95)00071-n · Cited by 1,021
Dean, C. C., Blamey, J., Florin, N. H., Al-Jeboori, M. J., & Fennell, P. S. (2011) · Chemical Engineering Research and Design · doi:10.1016/j.cherd.2010.10.013 · Cited by 375
Capture of CO2 from combustion gases in a fluidized bed of CaO
Abanades, J. C., Anthony, E. J., Lu, D. Y., Salvador, C., & Alvarez, D. (2004) · AIChE Journal · doi:10.1002/aic.10132 · Cited by 373
Perejón, A., Romeo, L. M., Lara, Y., Lisbona, P., Martínez, A., & Valverde, J. M. (2016) · Applied Energy · doi:10.1016/j.apenergy.2015.10.121 · Cited by 367
Metadata
- Authors
- Bhatia, S. K., & Perlmutter, D. D.
- Venue
- AIChE Journal
- Publisher
- Wiley
- Published
- 1983-01
- Volume
- 29
- Issue
- 1
- Pages
- 79-86
- ISSN
- 0001-1541 (ISSN-L)
- 1547-5905
- OpenAlex
- W2028889408
- Cited by
- 657
- References
- 1
- FWCI
- 6.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bhatia, S. K., & Perlmutter, D. D. (1983). Effect of the product layer on the kinetics of the CO2‐lime reaction. AIChE Journal. https://doi.org/10.1002/aic.690290111
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.