Kinetische Behandlung der Keimbildung in übersättigten Dämpfen
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The equations of the individual processes of self nucleation are utilized through an electrical analogy to obtain the nucleation frequency. This process is shown to be shorter and less subject to error than that of previous investigators since the appearance of indeterminant integration constants is completely avoided. With the nucleation frequencies of crystals and spheres the Ostwald law of stages is reviewed and modified.
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High reaction temperature and a high degree of solute supersaturation can accelerate nucleation.
“High reaction temperature and a high degree of solute supersaturation (i.e., the ratio of saturation solute concentrations to equilibrium solute concentration) can accelerate nucleation.”
From Carbon-Supported Pt-Based Alloy Electrocatalysts for the Oxygen Reduction Reaction in Polymer Electrolyte Membrane Fuel Cells: Particle Size, Shape, and Composition Manipulation and Their Impact to Activity (2015) · cites this paper as [196]
In the crystal-growth discussion (page unavailable), the paper says that, unless supersaturation is too high, a considerable time elapses before a new nucleus forms. That supports the supersaturation part for vapor, but the copy does not establish that high reaction temperature accelerates nucleation or address supersaturation defined by solute concentrations. (LLM, conf=0.84)
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Cites
Keimbildung in übersättigten Gebilden
Volmer, M., & Weber, Α. (1926) · Zeitschrift für Physikalische Chemie · doi:10.1515/zpch-1926-11927 · Cited by 1,936 · see citing works
Keimbildungsgeschwindigkeit in übersättigten Dämpfen
Farkas, L. (1927) · Zeitschrift für Physikalische Chemie · doi:10.1515/zpch-1927-12513 · Cited by 504 · see citing works
Zur kinetischen Ableitung der Keimbildungsgeschwindigkeit
Kaischew, R., & Stranski, I. N. (1934) · Zeitschrift für Physikalische Chemie · doi:10.1515/zpch-1934-2628 · Cited by 113 · see citing works
ÜBER KEIMBILDUNG UND KEIMWIRKUNG ALS SPEZIALFÄLLE DER HETEROGENEN KATALYSE
Volmer, M. (1929) · Zeitschrift für Elektrochemie und angewandte physikalische Chemie · doi:10.1002/bbpc.192900026 · Cited by 71 · see citing works
Zur Energetik von Oberflächenvorgängen
Kossel, W. (1934) · Annalen der Physik · doi:10.1002/andp.19344130502 · Cited by 67 · see citing works
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Reaction-rate theory: fifty years after Kramers
Hänggi, P., Talkner, P., & Borkovec, M. (1990) · Reviews of Modern Physics · doi:10.1103/revmodphys.62.251 · Cited by 6,154 · see citing works
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Colloidal Stabilization of Calcium Carbonate Prenucleation Clusters with Silica
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Observation of Anomalously Large Supercooling in Carbon Dioxide
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Large nucleation distances from impurities in the cosmological quark-hadron transition
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- Authors
- Becker, R., & Döring, W.
- Affiliations
- Technische Universität Berlin (DE)
- Venue
- Annalen der Physik
- Publisher
- Wiley
- Published
- 1935-01
- Volume
- 416
- Issue
- 8
- Pages
- 719-752
- ISSN
- 0003-3804 (ISSN-L)
- 1521-3889
- OpenAlex
- W2047137396
- Cited by
- 3,155
- References
- 5
- Citations by year
- 2026: 92 · 2025: 116 · 2024: 90 · 2023: 94 · 2022: 93 · 2021: 104 · 2020: 92 · 2019: 97 · 2018: 88 · 2017: 83 · 2016: 116 · 2015: 102 · 2014: 78 · 2013: 79 · 2012: 66
- FWCI
- 2.70
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Locations
- Annalen der Physik (publishedVersion)
- University of North Texas Digital Library (University of North Texas) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Crystallization and Solubility Studies
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › nanoparticles nucleation surface interactions
- Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
- Keywords
- self-nucleation, supersaturated vapor, nucleation rate, electrical analogy, crystal nucleation
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