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Cited by 325

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Multiple Phases of Molybdenum Carbide as Electrocatalysts for the Hydrogen Evolution Reaction

Wan, Cheng, Regmi, Yagya N., Leonard, Brian M.·2014·Angewandte Chemie

Abstract

Molybdenum carbide has been proposed as a possible alternative to platinum for catalyzing the hydrogen evolution reaction (HER). Previous studies were limited to only one phase, β‐Mo 2 C with an Fe 2 N structure. Here, four phases of Mo‐C were synthesized and investigated for their electrocatalytic activity and stability for HER in acidic solution. All four phases were synthesized from a unique amine–metal oxide composite material including γ‐MoC with a WC type structure which was stabilized for the first time as a phase pure nanomaterial. X‐ray photoelectron spectroscopy (XPS) and valence band studies were also used for the first time on γ‐MoC. γ‐MoC exhibits the second highest HER activity among all four phases of molybdenum carbide, and is exceedingly stable in acidic solution.

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Research works printed but not linked: 7

  1. Press S., 2010, Encyclopedia of Global Resources, Vol. 3, 772
  2. 10.1039/c3cc46551a · doi:10.1039/c3cc46551a
  3. 10.1007/BF00903803 · doi:10.1007/bf00903803
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  6. 10.1016/j.jcat.2010.04.004 · doi:10.1016/j.jcat.2010.04.004
  7. 10.1016/S0009-2614(00)01414-7 · doi:10.1016/s0009-2614(00)01414-7

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Metadata

Authors
Wan, C., Regmi, Y. N., & Leonard, B. M.
Venue
Angewandte Chemie
Publisher
Wiley
Published
2014-05-14
Volume
126
Issue
25
Pages
6525-6528
ISSN
  • 0044-8249 (ISSN-L)
  • 1521-3757
OpenAlex
W4239441456
Cited by
325
References
22
FWCI
10.26
Type
journal article
Language
de
Open access
closed

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CoChat. (2026). Citation check: Multiple Phases of Molybdenum Carbide as Electrocatalysts for the Hydrogen Evolution Reaction. https://app.cochat.ai/papers/10.1002/ange.201402998
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Wan, C., Regmi, Y. N., & Leonard, B. M. (2014). Multiple Phases of Molybdenum Carbide as Electrocatalysts for the Hydrogen Evolution Reaction. Angewandte Chemie. https://doi.org/10.1002/ange.201402998

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