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A Fast Deposition‐Crystallization Procedure for Highly Efficient Lead Iodide Perovskite Thin‐Film Solar Cells

Xiao, Manda, Huang, Fuzhi, Huang, Wenchao, Dkhissi, Yasmina, Zhu, Ye, Etheridge, Joanne, Gray‐Weale, Angus, Bach, Udo, Cheng, Yi‐Bing, Spiccia, Leone·2014·Angewandte Chemie

Abstract

Thin‐film photovoltaics based on alkylammonium lead iodide perovskite light absorbers have recently emerged as a promising low‐cost solar energy harvesting technology. To date, the perovskite layer in these efficient solar cells has generally been fabricated by either vapor deposition or a two‐step sequential deposition process. We report that flat, uniform thin films of this material can be deposited by a one‐step, solvent‐induced, fast crystallization method involving spin‐coating of a DMF solution of CH 3 NH 3 PbI 3 followed immediately by exposure to chlorobenzene to induce crystallization. Analysis of the devices and films revealed that the perovskite films consist of large crystalline grains with sizes up to microns. Planar heterojunction solar cells constructed with these solution‐processed thin films yielded an average power conversion efficiency of 13.9±0.7 % and a steady state efficiency of 13 % under standard AM 1.5 conditions.

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Metadata

Authors
Xiao, M., Huang, F., Huang, W., Dkhissi, Y., Zhu, Y., Etheridge, J., Gray‐Weale, A., Bach, U., Cheng, Y., & Spiccia, L.
Venue
Angewandte Chemie
Publisher
Wiley
Published
2014-07-22
Volume
126
Issue
37
Pages
10056-10061
ISSN
  • 0044-8249 (ISSN-L)
  • 1521-3757
OpenAlex
W4255078311
Cited by
714
References
1
FWCI
65.09
Type
journal article
Language
de
Open access
closed

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CoChat. (2026). Citation check: A Fast Deposition‐Crystallization Procedure for Highly Efficient Lead Iodide Perovskite Thin‐Film Solar Cells. https://app.cochat.ai/papers/10.1002/ange.201405334
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Xiao, M., Huang, F., Huang, W., Dkhissi, Y., Zhu, Y., Etheridge, J., Gray‐Weale, A., Bach, U., Cheng, Y., & Spiccia, L. (2014). A Fast Deposition‐Crystallization Procedure for Highly Efficient Lead Iodide Perovskite Thin‐Film Solar Cells. Angewandte Chemie. https://doi.org/10.1002/ange.201405334

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