The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
MoS2 Nanoflowers with Expanded Interlayers as High‐Performance Anodes for Sodium‐Ion Batteries
Abstract
MoS 2 nanoflowers with expanded interlayer spacing of the (002) plane were synthesized and used as high‐performance anode in Na‐ion batteries. By controlling the cut‐off voltage to the range of 0.4–3 V, an intercalation mechanism rather than a conversion reaction is taking place. The MoS 2 nanoflower electrode shows high discharge capacities of 350 mAh g−1 at 0.05 A g−1, 300 mAh g−1 at 1 A g−1, and 195 mAh g−1 at 10 A g−1. An initial capacity increase with cycling is caused by peeling off MoS 2 layers, which produces more active sites for Na+ storage. The stripping of MoS 2 layers occurring in charge/discharge cycling contributes to the enhanced kinetics and low energy barrier for the intercalation of Na+ ions. The electrochemical reaction is mainly controlled by the capacitive process, which facilitates the high‐rate capability. Therefore, MoS 2 nanoflowers with expanded interlayers hold promise for rechargeable Na‐ion batteries.
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Citations
Cites
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
Chhowalla, M., Shin, H. S., Eda, G., Li, L.-J., Loh, K. P., & Zhang, H. (2013) · Nature Chemistry · doi:10.1038/nchem.1589 · Cited by 10,034
Na 3 V 2 (PO 4 ) 3 @C core–shell nanocomposites for rechargeable sodium-ion batteries
Duan, W., Zhu, Z., Li, H., Hu, Z., Zhang, K., Cheng, F., & Chen, J. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta00106k · Cited by 411
Self-citation
Cited by
Recent development of two-dimensional transition metal dichalcogenides and their applications
Choi, W., Choudhary, N., Han, G. H., Park, J., Akinwande, D., & Lee, Y. H. (2017) · Materials Today · doi:10.1016/j.mattod.2016.10.002 · Cited by 2,769
Nanostructured Mo-based electrode materials for electrochemical energy storage
Hu, X., Zhang, W., Liu, X., Mei, Y., & Huang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00350k · Cited by 711
Solution‐Processed Two‐Dimensional MoS2 Nanosheets: Preparation, Hybridization, and Applications
Zhang, X., Lai, Z., Tan, C., & Zhang, H. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201509933 · Cited by 678
The Application of Metal Sulfides in Sodium Ion Batteries
Xiao, Y., Lee, S. H., & Sun, Y. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601329 · Cited by 616
Synthesis, stabilization and applications of 2-dimensional 1T metallic MoS 2
Shi, S., Sun, Z., & Hu, Y. H. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta08152b · Cited by 374
Metadata
- Authors
- Hu, Z., Wang, L., Zhang, K., Wang, J., Cheng, F., Tao, Z., & Chen, J.
- Venue
- Angewandte Chemie
- Publisher
- Wiley
- Published
- 2014-09-22
- Volume
- 126
- Issue
- 47
- Pages
- 13008-13012
- ISSN
- 0044-8249 (ISSN-L)
- 1521-3757
- OpenAlex
- W4234910170
- Cited by
- 323
- References
- 2
- FWCI
- 24.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hu, Z., Wang, L., Zhang, K., Wang, J., Cheng, F., Tao, Z., & Chen, J. (2014). MoS2 Nanoflowers with Expanded Interlayers as High‐Performance Anodes for Sodium‐Ion Batteries. Angewandte Chemie. https://doi.org/10.1002/ange.201407898
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