The DOI matches its Crossref record; 14 of the 14 references it cites were found in a registry or an index.
Phosphorus‐Modified Tungsten Nitride/Reduced Graphene Oxide as a High‐Performance, Non‐Noble‐Metal Electrocatalyst for the Hydrogen Evolution Reaction
Abstract
Phosphorus‐modified tungsten nitride/reduced graphene oxide (P‐WN/rGO) is designed as a high‐efficient, low‐cost electrocatalyst for the hydrogen evolution reaction (HER). WN (ca. 3 nm in size) on rGO is first synthesized by using the H 3[PO 4(W 3 O 9)4] cluster as a W source. Followed by phosphorization, the particle size increase slightly to about 4 nm with a P content of 2.52 at %. The interaction of P with rGO and WN results in an obvious increase of work function, being close to Pt metal. The P‐WN/rGO exhibits low onset overpotential of 46 mV, Tafel slope of 54 mV dec−1, and a large exchange current density of 0.35 mA cm−2 in acid media. It requires overpotential of only 85 mV at current density of 10 mA cm−2, while remaining good stability in accelerated durability testing. This work shows that the modification with a second anion is powerful way to design new catalysts for HER.
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Cites
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
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MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
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Alternative energy technologies
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Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
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Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution
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Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
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Cited by
Chen, Z., Song, Y., Cai, J., Zheng, X., Han, D., Wu, Y., Zang, Y., Niu, S., Liu, Y., Zhu, J., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201801834 · Cited by 1,075
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Gu, Y., Wu, A., Jiao, Y., Zheng, H., Wang, X., Xie, Y., Wang, L., Tian, C., & Fu, H. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202016102 · Cited by 363
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Metadata
- Authors
- Yan, H., Tian, C., Wang, L., Wu, A., Meng, M., Zhao, L., & Fu, H.
- Venue
- Angewandte Chemie
- Publisher
- Wiley
- Published
- 2015-03-30
- Volume
- 127
- Issue
- 21
- Pages
- 6423-6427
- ISSN
- 0044-8249 (ISSN-L)
- 1521-3757
- OpenAlex
- W4235567805
- Cited by
- 165
- References
- 14
- FWCI
- 6.06
- Type
- journal article
- Language
- de
- Open access
- closed
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- Yan, H., Tian, C., Wang, L., Wu, A., Meng, M., Zhao, L., & Fu, H. (2015). Phosphorus‐Modified Tungsten Nitride/Reduced Graphene Oxide as a High‐Performance, Non‐Noble‐Metal Electrocatalyst for the Hydrogen Evolution Reaction. Angewandte Chemie. https://doi.org/10.1002/ange.201501419
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