The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Surface Oxides of Carbon
Abstract
On oxidation of graphitic carbon, acidic surface oxides (or hydroxides in the presence of water) are formed at the boundaries of the carbon layers. It was found that the reaction of oxygen with microcrystalline carbon at 400–450°C yields four groups of different acidities. One strongly acidic group and one weakly acidic carboxyl group have been detected, as well as a phenolic hydroxyl group; a carbonyl group is probably also present. With dissolved oxidizing agents, one equivalent of another strongly acidic carboxyl group is formed in addition at room temperature. The possible constitutions of the acidic surface oxides are discussed. Chemically detectable surface oxides are also formed on the surface of diamond. In the presence of oxygen at 800–900°C under reduced pressure, diamond is transformed into black carbon. Surface oxides play a part in this transformation.
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Citations
Cites
Adsorption of Gases in Multimolecular Layers
Brunauer, S., Emmett, P. H., & Teller, E. (1938) · Journal of the American Chemical Society · doi:10.1021/ja01269a023 · Cited by 28,156
Cited by
Surface chemistry variations among a series of laboratory-produced biochars
Mukherjee, A., Zimmerman, A. R., & Harris, W. (2011) · Geoderma · doi:10.1016/j.geoderma.2011.04.021 · Cited by 1,171
Xiao, X., Chen, B., Chen, Z., Zhu, L., & Schnoor, J. L. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.7b06487 · Cited by 914
Two‐Dimensional Polymers: Just a Dream of Synthetic Chemists?
Sakamoto, J., van Heijst, J., Lukin, O., & Schlüter, A. D. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200801863 · Cited by 734
Effect of different oxidizing agent treatments on the surface properties of activated carbons
Pradhan, B. K., & Sandle, N. K. (1999) · Carbon · doi:10.1016/s0008-6223(98)00328-5 · Cited by 538
Deshmukh, A. A., Mhlanga, S. D., & Coville, N. J. (2010) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2010.06.017 · Cited by 354
Metadata
- Authors
- Boehm, H. ‐., Diehl, E., Heck, W., & Sappok, R.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1964-10
- Volume
- 3
- Issue
- 10
- Pages
- 669-677
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2068990400
- Cited by
- 544
- References
- 1
- FWCI
- 3.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- Boehm, H. ‐., Diehl, E., Heck, W., & Sappok, R. (1964). Surface Oxides of Carbon. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.196406691
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
