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The Composition and Conformation of Sugars in Solution
Abstract
The conformations of the aldoses in solution, and the compositions of the equilibrium mixtures formed from aldoses after dissolution in water, have been determined by NMR spectroscopy. Calculations based on non‐bonded interactions and on the anomeric effect account for the observed conformations, and allow an approximate prediction of the α:β ratio of pyranoses in equilibrium and of the extent of anhydride formation from sugars in acid solution. In certain circumstances the furanose forms are more stable than the pyranose forms.
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Cited by
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Román-Leshkov, Y., & Davis, M. E. (2011) · ACS Catalysis · doi:10.1021/cs200411d · Cited by 401
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Rodríguez, L., López, A., Moyna, G., Seoane, G. A., Davyt, D., Vázquez, Á., Hernández, G., & Carrera, I. (2022) · ACS Omega · doi:10.1021/acsomega.2c00795 · Cited by 30
Metadata
- Authors
- Angyal, S. J.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1969-03
- Volume
- 8
- Issue
- 3
- Pages
- 157-166
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W1984900762
- Cited by
- 422
- References
- 0
- FWCI
- 15.11
- Type
- journal article
- Language
- en
- Open access
- closed
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- Angyal, S. J. (1969). The Composition and Conformation of Sugars in Solution. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.196901571
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
