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Photochemical Hole Burning: A Spectroscopic Study of Relaxation Processes in Polymers and Glasses
Abstract
Photochemical hole burning is a special type of saturation spectroscopy in the optical domain having many analogies with NMR methods. The holes, which are burnt with laser irradiation, appear as small indentations in the absorption spectra of dye molecules which are doped into a polymer or glass in minute concentrations. Based on their narrow line width, photochemical holes can be regarded as highly sensitive spectroscopic probes. They can be used to detect small perturbations of the system by external parameters, giving rise to line‐shifts and broadenings. Besides the many well documented, spectroscopic applications of hole burning, it may offer interesting future developments for the spectroscopy of biomolecules and for high‐density data storage.
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Citations
Cites
Absence of Diffusion in Certain Random Lattices
Anderson, P. W. (1958) · Physical Review · doi:10.1103/physrev.109.1492 · Cited by 12,468
Cited by
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Demchenko, A. P. (2002) · Luminescence · doi:10.1002/bio.671 · Cited by 470
Single-molecule spectroscopy and imaging over the decades
Moerner, W. E., Shechtman, Y., & Wang, Q. (2015) · Faraday Discussions · doi:10.1039/c5fd00149h · Cited by 103
Metadata
- Authors
- Friedrich, J., & Haarer, D.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1984-02
- Volume
- 23
- Issue
- 2
- Pages
- 113-140
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2156473644
- Cited by
- 430
- References
- 1
- FWCI
- 17.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Friedrich, J., & Haarer, D. (1984). Photochemical Hole Burning: A Spectroscopic Study of Relaxation Processes in Polymers and Glasses. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.198401131
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