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The Taming of Cyclobutadiene
Abstract
The taming of cyclobutadiene was accomplished in the interior of the hemicarcerand 1. Cyclobutadiene is a stable compound with a singlet ground state when it is synthesized in the interior of 1. In order to synthesize the incarcerated cyclobutadiene and to characterize its structure, one bimolecular, three photochemical, and two thermal reactions were carried out in the interior of 1. The authors consider it both realistic and useful to regard the internal phase of carcerands and hemicarcerands as a new state of matter.
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Citations
Cited by
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Chen, Z., Wannere, C. S., Corminboeuf, C., Puchta, R., & Schleyer, P. V. R. (2005) · Chemical Reviews · doi:10.1021/cr030088+ · Cited by 3,847
Rosenberg, M., Dahlstrand, C., Kilså, K., & Ottosson, H. (2014) · Chemical Reviews · doi:10.1021/cr300471v · Cited by 505
Is cyclobutadiene really highly destabilized by antiaromaticity?
Wu, J. I.-C., Mo, Y., Evangelista, F. A., & von Ragué Schleyer, P. (2012) · Chemical Communications · doi:10.1039/c2cc33521b · Cited by 85
A Short History of Cyclocarbons
Anderson, H. L., Patrick, C. W., Scriven, L. M., & Woltering, S. L. (2021) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20200345 · Cited by 68
Hong, C., Baltazar, J., & Tovar, J. D. (2022) · European Journal of Organic Chemistry · doi:10.1002/ejoc.202101343 · Cited by 68
Metadata
- Authors
- Cram, D. J., Tanner, M. E., & Thomas, R.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1991-08
- Volume
- 30
- Issue
- 8
- Pages
- 1024-1027
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2136284957
- Cited by
- 525
- References
- 0
- FWCI
- 10.97
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cram, D. J., Tanner, M. E., & Thomas, R. (1991). The Taming of Cyclobutadiene. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.199110241
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