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Cited by 470

The DOI matches its Crossref record; 61 of the 61 references it cites were found in a registry or an index.

Ultramicroelectrodes in Electrochemistry

Heinze, Jürgen·1993·Angewandte Chemie International Edition in English

Abstract

In the 1950s and 1960s fundamental developments in electrochemical methods included voltammetry and low signal techniques. A generation later, the discovery of the unusual properties of ultramicroelectrodes has opened new possibilities of analyzing electrode processes. The changes in mass transport conditions bring about extremely high current densities at ultramicroelectrodes, whereas the currents themselves become very small. This little‐noticed phenomenon allows for many electroanalytical applications that are not possible with conventional electrodes, especially experiments in solutions with very low electrolyte concentrations, in nonpolar solvents, in solids, and even in gases. In addition, two factors— changes in the experimental time scale at low scan rates because of the size of the electrode, and insignificant iR effects at very high scan rates—make it possible to study very fast homogeneous and heterogeneous electrode processes.

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Metadata

Authors
Heinze, J.
Venue
Angewandte Chemie International Edition in English
Publisher
Wiley
Published
1993-09
Volume
32
Issue
9
Pages
1268-1288
ISSN
0570-0833 (ISSN-L)
OpenAlex
W2102445313
Cited by
470
References
61
FWCI
10.44
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Ultramicroelectrodes in Electrochemistry. https://app.cochat.ai/papers/10.1002/anie.199312681
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Heinze, J. (1993). Ultramicroelectrodes in Electrochemistry. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.199312681

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