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Three‐Dimensional Framework with Channeling Cavities for Small Molecules: {[M2(4, 4′‐bpy)3(NO3)4]·xH2O}n (M Co, Ni, Zn)
Abstract
Reversible adsorption of gases distinguishes the coordination polymers {[M2(4,4′-bpy)3(NO3)4](H2O)x}n (M = Co., x = 4; M = Ni, x = 4; M = Zn, x = 2), which are formed from M(NO3)2 and 4,4′-bipyridine in acetone/ethanol. The channeling cavities in the crystal frameworks (shown schematically on the right) have dimensions of about 3 × 6 Å along the a axis and about 3 × 3 Å along the b axis, and reversibly adsorb CH4, N2, and O2 in the pressure range of 1–36 atm without deformation of the crystal framework.
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Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
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New synthetic routes towards MOF production at scale
Rubio-Martinez, M., Avci-Camur, C., Thornton, A. W., Imaz, I., Maspoch, D., & Hill, M. R. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00109f · Cited by 990
Ligand design for functional metal–organic frameworks
Almeida Paz, F. A., Klinowski, J., Vilela, S. M. F., Tomé, J. P. C., Cavaleiro, J. A. S., & Rocha, J. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15055c · Cited by 855
A flexible interpenetrating coordination framework with a bimodal porous functionality
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Metadata
- Authors
- Kondo, M., Yoshitomi, T., Matsuzaka, H., Kitagawa, S., & Seki, K.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1997-09
- Volume
- 36
- Issue
- 16
- Pages
- 1725-1727
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2084024682
- Cited by
- 1,239
- References
- 1
- FWCI
- 32.62
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kondo, M., Yoshitomi, T., Matsuzaka, H., Kitagawa, S., & Seki, K. (1997). Three‐Dimensional Framework with Channeling Cavities for Small Molecules: {[M2(4, 4′‐bpy)3(NO3)4]·xH2O}n (M Co, Ni, Zn). Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.199717251
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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