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Sergeants‐and‐Soldiers Principle in Chiral Columnar Stacks of Disc‐Shaped Molecules with C3 Symmetry
Open accessAbstract
Extremely effective cooperative effects operate during the formation of chiral stacks of C3-symmetrical molecules in alkane solvents (a molecule is depicted on the right). The sergeants-and-soldiers principles as well as chiral solvation lead to a preferred helical sense in the columnar aggregates. The amplification of chirality in dynamic systems shows the precision in aggregation.
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Citations
Cited by
Supramolecular Chirality in Self-Assembled Systems
Liu, M., Zhang, L., & Wang, T. (2015) · Chemical Reviews · doi:10.1021/cr500671p · Cited by 2,250
Yashima, E., Ousaka, N., Taura, D., Shimomura, K., Ikai, T., & Maeda, K. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00354 · Cited by 2,004
Detection and Amplification of Chirality by Helical Polymers
Yashima, E., Maeda, K., & Nishimura, T. (2004) · Chemistry – A European Journal · doi:10.1002/chem.200305295 · Cited by 543
Complete asymmetric induction of supramolecular chirality in a hydrogen-bonded assembly
Prins, L. J., Huskens, J., de Jong, F., Timmerman, P., & Reinhoudt, D. N. (1999) · Nature · doi:10.1038/19053 · Cited by 481
Possible chemical and physical scenarios towards biological homochirality
Sallembien, Q., Bouteiller, L., Crassous, J., & Raynal, M. (2022) · Chemical Society Reviews · doi:10.1039/d1cs01179k · Cited by 186
Metadata
- Authors
- Palmans, A. R. A., Vekemans, J. A. J. M., Havinga, E. E., & Meijer, E. W.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1997-12-15
- Volume
- 36
- Issue
- 23
- Pages
- 2648-2651
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2100849404
- Cited by
- 383
- References
- 0
- FWCI
- 8.66
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Sergeants‐and‐Soldiers Principle in Chiral Columnar Stacks of Disc‐Shaped Molecules with C3 Symmetry. https://app.cochat.ai/papers/10.1002/anie.199726481
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- Palmans, A. R. A., Vekemans, J. A. J. M., Havinga, E. E., & Meijer, E. W. (1997). Sergeants‐and‐Soldiers Principle in Chiral Columnar Stacks of Disc‐Shaped Molecules with C3 Symmetry. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.199726481
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
