The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Host–Guest Antenna Materials
Open accessAbstract
The focus of this review is on host–guest composites with photonic antenna properties. The material generally consists of cylindrical zeolite L crystals the channels of which are filled with dye molecules. The synthesis is based on the fact that molecules can diffuse into individual channels. This means that, under the appropriate conditions, they can also leave the zeolite by the same way. In some cases, however, it is desirable to block their way out by adding a closure molecule. Functionalization of the closure molecules allows tuning of, for example, wettability, refractive index, and chemical reactivity. The supramolecular organization of the dyes inside the channels is a first stage of organization. It allows light harvesting within a certain volume of a dye‐loaded nanocrystalline zeolite and radiationless transport to both ends of the cylinder or from the ends to the center. The second stage of organization is the coupling to an external acceptor or donor stopcock fluorophore at the ends of the channels, which can trap or inject electronic excitation energy. The third stage of organization is the coupling to an external device through a stopcock molecule. The wide‐ranging tunability of these highly organized materials offers fascinating new possibilities for exploring excitation‐energy‐transfer phenomena, and challenges for developing new photonic devices.
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Cites
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Lessons from nature about solar light harvesting
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Emerging applications of zeolites in catalysis, separation and host–guest assembly
Li, Y., & Yu, J. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00347-3 · Cited by 585
Advances in theory and their application within the field of zeolite chemistry
Van Speybroeck, V., Hemelsoet, K., Joos, L., Waroquier, M., Bell, R. G., & Catlow, C. R. A. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00029g · Cited by 516
Tailored crystalline microporous materials by post-synthesis modification
Valtchev, V., Majano, G., Mintova, S., & Pérez-Ramírez, J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35196j · Cited by 478
Tailoring Porphyrins and Chlorins for Self-Assembly in Biomimetic Artificial Antenna Systems
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Metadata
- Authors
- Calzaferri, G., Huber, S., Maas, H., & Minkowski, C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2003-08-13
- Volume
- 42
- Issue
- 32
- Pages
- 3732-3758
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2064875270
- Cited by
- 498
- References
- 29
- FWCI
- 17.71
- Type
- journal article
- Language
- en
- Open access
- bronze
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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