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Fluoride‐Ion Encapsulation within a Silsesquioxane Cage
Abstract
Taming the caged ion: The X-ray crystal structure of an octaphenyl octasilsesquioxane cage that encapsulates a fluoride ion is presented (see picture). The extent of the SiF interaction is low, which causes the cage geometry to not change significantly from that of a normal T8 structure. The crystal structure and the NMR data suggest the fluoride ion is essentially “naked”.
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Citations
Cited by
Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes
Cordes, D. B., Lickiss, P. D., & Rataboul, F. (2010) · Chemical Reviews · doi:10.1021/cr900201r · Cited by 1,613
The Bright Future of Unconventional σ/π‐Hole Interactions
Bauzá, A., Mooibroek, T. J., & Frontera, A. (2015) · ChemPhysChem · doi:10.1002/cphc.201500314 · Cited by 710
Advances in Anion Supramolecular Chemistry: From Recognition to Chemical Applications
Evans, N. H., & Beer, P. D. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201309937 · Cited by 572
Supramolecular fluorescent sensors: An historical overview and update
Guo, C., Sedgwick, A. C., Hirao, T., & Sessler, J. L. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213560 · Cited by 284
Cametti, M., & Rissanen, K. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35439j · Cited by 281
Metadata
- Authors
- Bassindale, A. R., Pourny, M., Taylor, P. G., Hursthouse, M. B., & Light, M. E.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2003-07-30
- Volume
- 42
- Issue
- 30
- Pages
- 3488-3490
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2154292886
- Cited by
- 165
- References
- 0
- FWCI
- 4.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bassindale, A. R., Pourny, M., Taylor, P. G., Hursthouse, M. B., & Light, M. E. (2003). Fluoride‐Ion Encapsulation within a Silsesquioxane Cage. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200351249
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
