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Highlights on contemporary recognition and sensing of fluoride anion in solution and in the solid state

Cametti, Massimo, Rissanen, Kari·2013·Chem. Soc. Rev.
DOI 10.1039/c2cs35439j
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Abstract

The fluoride anion has recently gained well deserved attention among the scientific community for its importance in many fields of human activities, but also for concerns on its effect on health and the environment. Although surprisingly overlooked in systematic studies in the past, fluoride has nowadays become a topical target in the field of anion recognition. A multitude of scientific reports are published every year where the establishment of efficient and specific interaction with fluoride is sought in polar and aqueous media. Here, the emphasis is directed to a detailed description of the most interesting contemporary studies in the field, with a particular focus given to those published in the last few years.

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  • HF may have relevance in biological systems, as it does in host-guest chemistry.

    “the relatively high pKa of HF means that this species may have relevance in biological systems, as it does in host-guest chemistry(10, 32).”

    From Membrane exporters of fluoride ion (2021) · cites this paper as [32]

  • F− prefers approximately one-two fewer ligands than Cl−.

    “F− prefers approximately one-two fewer ligands than Cl− (31–34)”

    From Membrane exporters of fluoride ion (2021) · cites this paper as [32]

  • Small molecule hosts designed for fluoride recognition commonly utilize between four and six hydrogen bond donors.

    “small molecule hosts designed for fluoride recognition commonly utilize between four and six hydrogen bond donors (32).”

    From Membrane exporters of fluoride ion (2021) · cites this paper as [32]

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Metadata

Authors
Cametti, M., & Rissanen, K.
Venue
Chem. Soc. Rev.
Publisher
Royal Society of Chemistry (RSC)
Published
2013
Volume
42
Issue
5
Pages
2016-2038
ISSN
  • 0306-0012
  • 1460-4744
DOI
10.1039/c2cs35439j
Cited by
281
References
1
Language
en

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