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Tuning Reaction Rates by Lateral Strain in a Palladium Monolayer
Abstract
Stretching exercises: The electrochemical behavior of pseudomorphic palladium monolayers (PdML) on various single-crystal electrodes is investigated (see picture) to demonstrate the influence of lateral compression and dilation on surface activity. The adsorption behavior and the catalytic activity for formic acid electrooxidation varies dramatically depending on whether the palladium monolayer is compressed or dilated by the single-crystal electrode.
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Cited by
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Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts
Strasser, P., Koh, S., Anniyev, T., Greeley, J., More, K., Yu, C., Liu, Z., Kaya, S., Nordlund, D., Ogasawara, H., et al. (2010) · Nature Chemistry · doi:10.1038/nchem.623 · Cited by 2,984
Stamenkovic, V., Mun, B. S., Mayrhofer, K. J. J., Ross, P. N., Markovic, N. M., Rossmeisl, J., Greeley, J., & Nørskov, J. K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200504386 · Cited by 2,109
Zheng, Y., Jiao, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201407031 · Cited by 2,046
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Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Metadata
- Authors
- Kibler, L. A., El‐Aziz, A. M., Hoyer, R., & Kolb, D. M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2005-03-22
- Volume
- 44
- Issue
- 14
- Pages
- 2080-2084
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2116106887
- Cited by
- 573
- References
- 0
- FWCI
- 12.25
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kibler, L. A., El‐Aziz, A. M., Hoyer, R., & Kolb, D. M. (2005). Tuning Reaction Rates by Lateral Strain in a Palladium Monolayer. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200462127
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