Cited by 2,109Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCO2 Reduction Techniques and Catalysts

Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure

Stamenkovic, Vojislav, Mun, Bongjin Simon, Mayrhofer, Karl J. J., Ross, Philip N., Markovic, Nenad M., Rossmeisl, Jan, Greeley, Jeff, Nørskov, Jens K.·2006·Angewandte Chemie International Edition

Abstract

Going platinum: The theoretical description of electrocatalytic phenomena is extremely challenging. A simple, density functional theory based model has been developed that is able to give a semiquantitative description of the reaction kinetics for the electrocatalytic oxygen reduction on several platinum binary alloys, Pt3M (see graph).

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Crossref · 10.1002/anie.200504386

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  • A high d-band center benefits the adsorption of oxygen-containing species but leads to slow intermediate desorption and active site poisoning, while a low d-band center suffers from slow adsorption of oxygen and low kinetics.

    “A high d-band center benefits the adsorption of oxygen-containing species but leads to slow intermediate desorption and active site poisoning, while a low d-band center suffers from slow adsorption of oxygen and low kinetics [37,38].”

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Authors
Stamenkovic, V., Mun, B. S., Mayrhofer, K. J. J., Ross, P. N., Markovic, N. M., Rossmeisl, J., Greeley, J., & Nørskov, J. K.
Affiliations
  • Lawrence Berkeley National Laboratory (US)
  • Technical University of Denmark (DK)
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2006-04-21
Volume
45
Issue
18
Pages
2897-2901
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2115729799
Cited by
2,109
References
0
Citations by year
2026: 71 · 2025: 109 · 2024: 141 · 2023: 110 · 2022: 111 · 2021: 121 · 2020: 161 · 2019: 134 · 2018: 137 · 2017: 135 · 2016: 139 · 2015: 119 · 2014: 97 · 2013: 117 · 2012: 105
FWCI
34.35
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
  • JuSER (Forschungszentrum Jülich) (submittedVersion)
  • Max Planck Digital Library (submittedVersion)
  • Technical University of Denmark, DTU Orbit (Technical University of Denmark, DTU) (submittedVersion)
  • MPG.PuRe (Max Planck Society) (submittedVersion)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Keywords
oxygen reduction reaction, electrocatalysts, surface electronic structure, reaction kinetics, non-platinum catalysts

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