Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure
Abstract
Going platinum: The theoretical description of electrocatalytic phenomena is extremely challenging. A simple, density functional theory based model has been developed that is able to give a semiquantitative description of the reaction kinetics for the electrocatalytic oxygen reduction on several platinum binary alloys, Pt3M (see graph).
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A high d-band center benefits the adsorption of oxygen-containing species but leads to slow intermediate desorption and active site poisoning, while a low d-band center suffers from slow adsorption of oxygen and low kinetics.
“A high d-band center benefits the adsorption of oxygen-containing species but leads to slow intermediate desorption and active site poisoning, while a low d-band center suffers from slow adsorption of oxygen and low kinetics [37,38].”
From Recent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly (2023) · cites this paper as [37]
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- Authors
- Stamenkovic, V., Mun, B. S., Mayrhofer, K. J. J., Ross, P. N., Markovic, N. M., Rossmeisl, J., Greeley, J., & Nørskov, J. K.
- Affiliations
- Lawrence Berkeley National Laboratory (US)
- Technical University of Denmark (DK)
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2006-04-21
- Volume
- 45
- Issue
- 18
- Pages
- 2897-2901
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2115729799
- Cited by
- 2,109
- References
- 0
- Citations by year
- 2026: 71 · 2025: 109 · 2024: 141 · 2023: 110 · 2022: 111 · 2021: 121 · 2020: 161 · 2019: 134 · 2018: 137 · 2017: 135 · 2016: 139 · 2015: 119 · 2014: 97 · 2013: 117 · 2012: 105
- FWCI
- 34.35
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- JuSER (Forschungszentrum Jülich) (submittedVersion)
- Max Planck Digital Library (submittedVersion)
- Technical University of Denmark, DTU Orbit (Technical University of Denmark, DTU) (submittedVersion)
- MPG.PuRe (Max Planck Society) (submittedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- oxygen reduction reaction, electrocatalysts, surface electronic structure, reaction kinetics, non-platinum catalysts
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