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Cited by 275

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Calix[4]pyrrole: An Old yet New Ion‐Pair Receptor

Custelcean, Radu, Delmau, Lætitia H., Moyer, Bruce A., Sessler, Jonathan L., Cho, Won‐Seob, Gross, Dustin, Bates, Gareth W., Brooks, Simon J., Light, Mark E., Gale, Philip A.·2005·Angewandte Chemie International Edition
DOI 10.1002/anie.200462945
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Abstract

Ditopic cation–anion binding is revealed by solid-state studies of the anion-recognition behavior of the calix[4]pyrrole unit. Anion binding causes an electron-rich conelike cavity to be formed that can then bind large polarizable cations. Furthermore, complexation of calix[4]pyrrole with cesium carbonate results in dimerization, in which a single anion bridges two calix[4]pyrroles (see the crystal structure of the Cs2CO3 complex).

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Metadata

Authors
Custelcean, R., Delmau, L. H., Moyer, B. A., Sessler, J. L., Cho, W., Gross, D., Bates, G. W., Brooks, S. J., Light, M. E., & Gale, P. A.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2005-04-21
Volume
44
Issue
17
Pages
2537-2542
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
DOI
10.1002/anie.200462945
OpenAlex
W2163501366
Cited by
275
References
0
FWCI
11.31
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Calix[4]pyrrole: An Old yet New Ion‐Pair Receptor. https://app.cochat.ai/papers/10.1002/anie.200462945
The paper
Custelcean, R., Delmau, L. H., Moyer, B. A., Sessler, J. L., Cho, W., Gross, D., Bates, G. W., Brooks, S. J., Light, M. E., & Gale, P. A. (2005). Calix[4]pyrrole: An Old yet New Ion‐Pair Receptor. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200462945

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.