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Strong Means Slow: Dynamic Contributions to the Bulk Mechanical Properties of Supramolecular Networks
Abstract
Hold on tight: The dynamics, rather than thermodynamics, of reversible cross-links are the primary determinants of bulk viscosities in a family of supramolecular networks. This result comes from a study in which a series of structurally similar pincer complexes (see picture, OTf=CF3SO3−) that have different ligand-exchange dynamics is used to cross-link poly(4-vinylpyridine).
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Cited by
Supramolecular polymeric hydrogels
Appel, E. A., del Barrio, J., Loh, X. J., & Scherman, O. A. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35264h · Cited by 1,159
Malleable and Self-Healing Covalent Polymer Networks through Tunable Dynamic Boronic Ester Bonds
Cromwell, O. R., Chung, J., & Guan, Z. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03551 · Cited by 1,048
Characterization of supramolecular gels
Yu, G., Yan, X., Han, C., & Huang, F. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60080g · Cited by 626
Zhang, Z. P., Rong, M. Z., & Zhang, M. Q. (2018) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2018.03.002 · Cited by 586
Yount, W. C., Loveless, D. M., & Craig, S. L. (2005) · Journal of the American Chemical Society · doi:10.1021/ja054298a · Cited by 388
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Metadata
- Authors
- Yount, W. C., Loveless, D. M., & Craig, S. L.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2005-04-25
- Volume
- 44
- Issue
- 18
- Pages
- 2746-2748
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2131928429
- Cited by
- 260
- References
- 0
- FWCI
- 6.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yount, W. C., Loveless, D. M., & Craig, S. L. (2005). Strong Means Slow: Dynamic Contributions to the Bulk Mechanical Properties of Supramolecular Networks. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200500026
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