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Mesocrystals: Inorganic Superstructures Made by Highly Parallel Crystallization and Controlled Alignment
Open accessAbstract
Controlled self‐organization of nanoparticles can lead to new materials. The colloidal crystallization of non‐spherical nanocrystals is a reaction channel in many crystallization reactions. With additives, self‐organization can be stopped at an intermediary step—a mesocrystal—in which the primary units can still be identified. Mesocrystals were observed for various systems as kinetically metastable species or as intermediates in a crystallization reaction leading to single crystals with typical defects and inclusions. The control forces and mechanism of mesocrystal formation are largely unknown, but several mesocrystal properties are known. Mesocrystals are exiting examples of nonclassical crystallization, which does not proceed through ion‐by‐ion attachment, but by a modular nanobuilding‐block route. This path makes crystallization more independent of ion products or molecular solubility, it occurs without pH or osmotic pressure changes, and opens new strategies for crystal morphogenesis.
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Citations
Cites
Fluid supersaturation and crystallization in porous media
Putnis, A., Prieto, M., & Fernandez-Diaz, L. (1995) · Geological Magazine · doi:10.1017/s0016756800011389 · Cited by 192
Cited by
Crystallization by particle attachment in synthetic, biogenic, and geologic environments
De Yoreo, J. J., Gilbert, P. U. P. A., Sommerdijk, N. A. J. M., Penn, R. L., Whitelam, S., Joester, D., Zhang, H., Rimer, J. D., Navrotsky, A., Banfield, J. F., et al. (2015) · Science · doi:10.1126/science.aaa6760 · Cited by 2,137
Self-citationControlling Mineral Morphologies and Structures in Biological and Synthetic Systems
Meldrum, F. C., & Cölfen, H. (2008) · Chemical Reviews · doi:10.1021/cr8002856 · Cited by 1,397
Self-citationGower, L. B. (2008) · Chemical Reviews · doi:10.1021/cr800443h · Cited by 1,086
Prenucleation clusters and non-classical nucleation
Gebauer, D., & Cölfen, H. (2011) · Nano Today · doi:10.1016/j.nantod.2011.10.005 · Cited by 682
Self-citationGe, X., Gu, C., Wang, X., & Tu, J. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta01659j · Cited by 372
Metadata
- Authors
- Cölfen, H., & Antonietti, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2005-09
- Volume
- 44
- Issue
- 35
- Pages
- 5576-5591
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2153653432
- Cited by
- 1,728
- References
- 1
- FWCI
- 39.64
- Type
- journal article
- Language
- en
- Open access
- green
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- Cölfen, H., & Antonietti, M. (2005). Mesocrystals: Inorganic Superstructures Made by Highly Parallel Crystallization and Controlled Alignment. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200500496
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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