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Recyclable Palladium Catalyst for Highly Selective α Alkylation of Ketones with Alcohols
Abstract
An air-stable, heterogeneous, and recyclable catalyst composed of palladium nanoparticles entrapped in aluminum hydroxide was applied to a highly selective α alkylation. A wide range of aliphatic and aromatic ketones and primary alcohols were coupled to prepare enones in an O2 atmosphere and ketones in an argon atmosphere (see scheme).
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Citations
Cited by
Efficient, Selective, and Recyclable Palladium Catalysts in Carbon−Carbon Coupling Reactions
Molnár, Á. (2011) · Chemical Reviews · doi:10.1021/cr100355b · Cited by 1,042
Heterogeneous Catalysts for the One-Pot Synthesis of Chemicals and Fine Chemicals
Climent, M. J., Corma, A., & Iborra, S. (2011) · Chemical Reviews · doi:10.1021/cr1002084 · Cited by 866
Integration of chemical catalysis with extractive fermentation to produce fuels
Anbarasan, P., Baer, Z. C., Sreekumar, S., Gross, E., Binder, J. B., Blanch, H. W., Clark, D. S., & Toste, F. D. (2012) · Nature · doi:10.1038/nature11594 · Cited by 385
Metadata
- Authors
- Kwon, M. S., Kim, N., Seo, S. H., Park, I. S., Cheedrala, R. K., & Park, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2005-10-25
- Volume
- 44
- Issue
- 42
- Pages
- 6913-6915
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2111413589
- Cited by
- 259
- References
- 0
- FWCI
- 7.34
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Recyclable Palladium Catalyst for Highly Selective α Alkylation of Ketones with Alcohols. https://app.cochat.ai/papers/10.1002/anie.200502422
- The paper
- Kwon, M. S., Kim, N., Seo, S. H., Park, I. S., Cheedrala, R. K., & Park, J. (2005). Recyclable Palladium Catalyst for Highly Selective α Alkylation of Ketones with Alcohols. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200502422
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
