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Transcription and Amplification of Molecular Chirality to Oppositely Biased Supramolecular π Helices
Abstract
Let's twist again: Transcription of molecular chirality from common stereogenic centers to amplified supramolecular chirality during the coassembly of gel-forming π-conjugated molecules by inverted helicity results in the formation of longitudinally fused M and P helices. This “sergeants and soldiers” approach to coassembly under stereomutation has been confirmed by CD and AFM techniques (see picture).
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Citations
Cited by
Yashima, E., Ousaka, N., Taura, D., Shimomura, K., Ikai, T., & Maeda, K. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00354 · Cited by 2,004
Ajayaghosh, A., & Praveen, V. K. (2007) · Accounts of Chemical Research · doi:10.1021/ar7000364 · Cited by 855
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Metadata
- Authors
- Ajayaghosh, A., Varghese, R., George, S. J., & Vijayakumar, C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2006-01-30
- Volume
- 45
- Issue
- 7
- Pages
- 1141-1144
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2156880177
- Cited by
- 214
- References
- 0
- FWCI
- 9.62
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Transcription and Amplification of Molecular Chirality to Oppositely Biased Supramolecular π Helices. https://app.cochat.ai/papers/10.1002/anie.200503142
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- Ajayaghosh, A., Varghese, R., George, S. J., & Vijayakumar, C. (2006). Transcription and Amplification of Molecular Chirality to Oppositely Biased Supramolecular π Helices. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200503142
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
