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Practical Synthesis of Amides from In Situ Generated Copper(I) Acetylides and Sulfonyl Azides
Abstract
A direct, simple, and efficient route from terminal alkynes to amides is achieved by their copper(I)-catalyzed reaction with sulfonyl azides (see scheme). The reaction proceeds with the in situ generation of copper(I) acetylides and represents a one-step formal oxidative hydration of a triple bond.
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Tornøe, C. W., Christensen, C., & Meldal, M. (2002) · The Journal of Organic Chemistry · doi:10.1021/jo011148j · Cited by 8,696
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Metadata
- Authors
- Cassidy, M. P., Raushel, J., & Fokin, V. V.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2006-04-27
- Volume
- 45
- Issue
- 19
- Pages
- 3154-3157
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2112869436
- Cited by
- 282
- References
- 1
- FWCI
- 13.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cassidy, M. P., Raushel, J., & Fokin, V. V. (2006). Practical Synthesis of Amides from In Situ Generated Copper(I) Acetylides and Sulfonyl Azides. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200503805
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
