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Mixed Mg/Li Amides of the Type R2NMgCl⋅LiCl as Highly Efficient Bases for the Regioselective Generation of Functionalized Aryl and Heteroaryl Magnesium Compounds
Abstract
Two are better than one: Mixed lithium-magnesium complexes of the type R2NMgCl⋅LiCl are kinetically highly active bases that convert a range of polyfunctional aromatic and heteroaromatic substrates into the corresponding magnesiated derivatives with high regioselectivity.
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Citations
Cites
TMP−Zincate as Highly Chemoselective Base for Directed Ortho Metalation
Kondo, Y., Shilai, M., Uchiyama, M., & Sakamoto, T. (1999) · Journal of the American Chemical Society · doi:10.1021/ja984263t · Cited by 309
Queguiner, G., Marsais, F., Snieckus, V., & Epsztajn, J. (1991) · Advances in Heterocyclic Chemistry · doi:10.1016/s0065-2725(08)60965-4 · Cited by 218
Cited by
3d Transition Metals for C–H Activation
Gandeepan, P., Müller, T., Zell, D., Cera, G., Warratz, S., & Ackermann, L. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00507 · Cited by 2,332
Deprotonative Metalation Using Ate Compounds: Synergy, Synthesis, and Structure Building
Mulvey, R. E., Mongin, F., Uchiyama, M., & Kondo, Y. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200604369 · Cited by 553
Chemoselectivity and the Curious Reactivity Preferences of Functional Groups
Afagh, N. A., & Yudin, A. K. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200901317 · Cited by 320
Gruszka, W., & Garden, J. A. (2022) · Chemical Communications · doi:10.1039/d1cc06594g · Cited by 20
Metadata
- Authors
- Krasovskiy, A., Krasovskaya, V., & Knochel, P.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2006-04-21
- Volume
- 45
- Issue
- 18
- Pages
- 2958-2961
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2166652514
- Cited by
- 507
- References
- 2
- FWCI
- 17.75
- Type
- journal article
- Language
- en
- Open access
- closed
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- Krasovskiy, A., Krasovskaya, V., & Knochel, P. (2006). Mixed Mg/Li Amides of the Type R2NMgCl⋅LiCl as Highly Efficient Bases for the Regioselective Generation of Functionalized Aryl and Heteroaryl Magnesium Compounds. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200504024
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