The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Deprotonative Metalation Using Ate Compounds: Synergy, Synthesis, and Structure Building
Abstract
Historically, single‐metal organometallic species such as organolithium compounds have been the reagents of choice in synthetic organic chemistry for performing deprotonation reactions. Over the past few years, a complementary new class of metalating agents has started to emerge. Owing to a variable central metal (magnesium, zinc, or aluminum), variable ligands (both in their nature and number), and a variable second metallic center (an alkali metal such as lithium or sodium), “ate” complexes are highly versatile bases that exhibit a synergic chemistry which cannot be replicated by the homometallic magnesium, zinc, or aluminum compounds on their own. Deprotonation accomplished by using these organometallic ate complexes has opened up new perspectives in organic chemistry with unprecedented reactivities and sometimes unusual and unpredictable regioselectivities.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
The chemistry of 2-oxazolines (1985–present)
Gant, T. G., & Meyers, A. I. (1994) · Tetrahedron · doi:10.1016/s0040-4020(01)86953-2 · Cited by 579
Krasovskiy, A., Krasovskaya, V., & Knochel, P. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200504024 · Cited by 507
Ziegler—Natta catalysts and polymerizations
Stannett, V. T. (1980) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(80)90229-5 · Cited by 461
Beak, P., & Snieckus, V. (1982) · Accounts of Chemical Research · doi:10.1021/ar00082a002 · Cited by 430
Taylor, M. S., Zalatan, D. N., Lerchner, A. M., & Jacobsen, E. N. (2005) · Journal of the American Chemical Society · doi:10.1021/ja044999s · Cited by 331
TMP−Zincate as Highly Chemoselective Base for Directed Ortho Metalation
Kondo, Y., Shilai, M., Uchiyama, M., & Sakamoto, T. (1999) · Journal of the American Chemical Society · doi:10.1021/ja984263t · Cited by 309
Self-citationÜber das Verhalten von Diphenylmetallen als Komplexbildner
Wittig, G., Meyer, F. J., & Lange, G. (1951) · Justus Liebigs Annalen der Chemie · doi:10.1002/jlac.19515710302 · Cited by 251
Selective Halogen−Magnesium Exchange Reaction via Organomagnesium Ate Complex
Inoue, A., Kitagawa, K., Shinokubo, H., & Oshima, K. (2001) · The Journal of Organic Chemistry · doi:10.1021/jo015597v · Cited by 245
Queguiner, G., Marsais, F., Snieckus, V., & Epsztajn, J. (1991) · Advances in Heterocyclic Chemistry · doi:10.1016/s0065-2725(08)60965-4 · Cited by 218
Mulvey, R. E. (2001) · Chemical Communications · doi:10.1039/b101576l · Cited by 203
Self-citation
Cited by
3d Transition Metals for C–H Activation
Gandeepan, P., Müller, T., Zell, D., Cera, G., Warratz, S., & Ackermann, L. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00507 · Cited by 2,332
Gaston, A. J., Greindl, Z., Morrison, C. A., & Garden, J. A. (2021) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.0c03145 · Cited by 45
The Role of Organoferrates in Iron‐Catalyzed Cross‐Couplings
Sandl, S., & Jacobi von Wangelin, A. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201914844 · Cited by 18
Clegg, W., Fleming, B. J., García-Álvarez, P., Hogg, L. M., Kennedy, A. R., Klett, J., Martínez-Martínez, A. J., Mulvey, R. E., Russo, L., & O'Hara, C. T. (2013) · Dalton Trans. · doi:10.1039/c2dt32176a · Cited by 3
Self-citation
Metadata
- Authors
- Mulvey, R. E., Mongin, F., Uchiyama, M., & Kondo, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2007-05-15
- Volume
- 46
- Issue
- 21
- Pages
- 3802-3824
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2043767622
- Cited by
- 553
- References
- 27
- FWCI
- 23.60
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Deprotonative Metalation Using Ate Compounds: Synergy, Synthesis, and Structure Building. https://app.cochat.ai/papers/10.1002/anie.200604369
- The paper
- Mulvey, R. E., Mongin, F., Uchiyama, M., & Kondo, Y. (2007). Deprotonative Metalation Using Ate Compounds: Synergy, Synthesis, and Structure Building. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200604369
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
