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From Vesicles to Helical Nanotubes: A Sergeant‐and‐Soldiers Effect in the Self‐Assembly of Oligo(p‐phenyleneethynylene)s
Abstract
Coassembly of short molecular wires OPE1 with chiral analogues OPE2, both of which are CD silent, exhibited a sergeant-and-soldiers effect that resulted in transformation of vesicular aggregates of OPE1 into CD-active helical nanotubes (see schematic picture), as revealed by CD, dynamic light scattering, and atomic force and transmission electron microscopies (TEM). OPE=oligo(p-phenyleneethynylene).
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Citations
Cited by
Yashima, E., Ousaka, N., Taura, D., Shimomura, K., Ikai, T., & Maeda, K. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00354 · Cited by 2,004
Ajayaghosh, A., & Praveen, V. K. (2007) · Accounts of Chemical Research · doi:10.1021/ar7000364 · Cited by 855
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Metadata
- Authors
- Ajayaghosh, A., Varghese, R., Mahesh, S., & Praveen, V. K.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2006-11-20
- Volume
- 45
- Issue
- 46
- Pages
- 7729-7732
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2161929578
- Cited by
- 208
- References
- 0
- FWCI
- 8.38
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ajayaghosh, A., Varghese, R., Mahesh, S., & Praveen, V. K. (2006). From Vesicles to Helical Nanotubes: A Sergeant‐and‐Soldiers Effect in the Self‐Assembly of Oligo(p‐phenyleneethynylene)s. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200603238
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