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N‐Heterocyclic Carbenes as Organocatalysts
Abstract
Organocatalyzed reactions represent an attractive alternative to metal‐catalyzed processes notably because of their lower cost and benign environmental impact in comparison to organometallic catalysis. In this context, N‐heterocyclic carbenes (NHCs) have been studied for their ability to promote primarily the benzoin condensation. Lately, dramatic progress in understanding their intrinsic properties and in their synthesis have made them available to organic chemists. This has resulted in a tremendous increase of their scope and in a true explosion of the number of papers reporting NHC‐catalyzed reactions. Here, we highlight the ever‐increasing number of reactions that can be promoted by N‐heterocyclic carbenes.
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Cites
Polymeric systems for controlled drug release
Uhrich, K. E., Cannizzaro, S. M., Langer, R. S., & Shakesheff, K. M. (1999) · Chemical Reviews · doi:10.1021/cr940351u · Cited by 2,633
Cited by
Heterocyclic Carbenes: Synthesis and Coordination Chemistry
Hahn, F. E., & Jahnke, M. C. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200703883 · Cited by 2,775
Chemistry and materials options of sustainable carbon materials made by hydrothermal carbonization
Titirici, M.-M., & Antonietti, M. (2010) · Chem. Soc. Rev. · doi:10.1039/b819318p · Cited by 1,255
Cu(I)-Catalyzed Click Chemistry in Glycoscience and Their Diverse Applications
Agrahari, A. K., Bose, P., Jaiswal, M. K., Rajkhowa, S., Singh, A. S., Hotha, S., Mishra, N., & Tiwari, V. K. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00920 · Cited by 445
Metal-NHC complexes: a survey of anti-cancer properties
Teyssot, M.-L., Jarrousse, A.-S., Manin, M., Chevry, A., Roche, S., Norre, F., Beaudoin, C., Morel, L., Boyer, D., Mahiou, R., et al. (2009) · Dalton Transactions · doi:10.1039/b906308k · Cited by 384
Organocatalysis in biorefining for biomass conversion and upgrading
Liu, D. (. J. )., & Chen, E. Y.-X. (2014) · Green Chem. · doi:10.1039/c3gc41934g · Cited by 101
Metadata
- Authors
- Marion, N., Díez‐González, S., & Nolan, S. P.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2007-04-12
- Volume
- 46
- Issue
- 17
- Pages
- 2988-3000
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2058367938
- Cited by
- 1,459
- References
- 1
- FWCI
- 58.10
- Type
- journal article
- Language
- en
- Open access
- closed
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