The DOI matches its Crossref record; 84 of the 84 references it cites were found in a registry or an index.
Amplification of Chirality in Dynamic Supramolecular Aggregates
Abstract
The quest to understand the origin of chirality in biological systems has evoked an intense search for nonlinear effects in catalysis and pathways to amplify slight enantiomeric excesses in racemates to give optically pure molecules. The amplification of chirality in polymeric systems as a result of cooperative processes has been intensely investigated. Ten years ago, this effect was shown for the first time in noncovalent dynamic supramolecular systems. Since then, it has become clear that a subtle interplay of noncovalent interactions such as hydrogen‐bonding, π–π stacking, and hydrophobic interactions is also sufficient to observe amplification of chirality in small molecules. Here we summarize the results obtained over the past decade and the general guidelines we can deduce from them. Predicting amplification of chirality is still impossible, but it appears to be a balance between different types of interactions, the formation of an intrinsically chiral object, and cooperative aggregation processes.
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Self-citationReversible Polymers Formed from Self-Complementary Monomers Using Quadruple Hydrogen Bonding
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Noncovalent Synthesis: Using Physical-Organic Chemistry To Make Aggregates
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Self-citationChiral Architectures from Macromolecular Building Blocks
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Cited by
Supramolecular Chirality in Self-Assembled Systems
Liu, M., Zhang, L., & Wang, T. (2015) · Chemical Reviews · doi:10.1021/cr500671p · Cited by 2,250
Yashima, E., Ousaka, N., Taura, D., Shimomura, K., Ikai, T., & Maeda, K. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00354 · Cited by 2,004
Perylene Bisimide Dye Assemblies as Archetype Functional Supramolecular Materials
Würthner, F., Saha-Möller, C. R., Fimmel, B., Ogi, S., Leowanawat, P., & Schmidt, D. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00188 · Cited by 1,737
Dendron-Mediated Self-Assembly, Disassembly, and Self-Organization of Complex Systems
Rosen, B. M., Wilson, C. J., Wilson, D. A., Peterca, M., Imam, M. R., & Percec, V. (2009) · Chemical Reviews · doi:10.1021/cr900157q · Cited by 1,204
Self-assembled π-stacks of functional dyes in solution: structural and thermodynamic features
Chen, Z., Lohr, A., Saha-Möller, C. R., & Würthner, F. (2009) · Chem. Soc. Rev. · doi:10.1039/b809359h · Cited by 1,051
Metadata
- Authors
- Palmans, A. R. A., & Meijer, E. W.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2007-11-23
- Volume
- 46
- Issue
- 47
- Pages
- 8948-8968
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2134830236
- Cited by
- 848
- References
- 84
- FWCI
- 18.41
- Type
- journal article
- Language
- en
- Open access
- closed
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