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Enhanced Cooperative Activation Effect in the Hydrolytic Kinetic Resolution of Epoxides on [Co(salen)] Catalysts Confined in Nanocages
Abstract
Being cagey: More than two chiral [Co(salen)] catalyst molecules can be confined in one nanocage of SBA-16 by reducing the pore entrance size by silylation. The [Co(salen)]/SBA-16 catalysts with more than two [Co(salen)] complexes in each cage show a significantly enhanced cooperative activation effect and exhibit much higher activity than the homogeneous [Co(salen)] catalyst in the hydrolytic kinetic resolution of epoxides (see scheme).
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Citations
Cites
Minton, A. P. (2001) · Journal of Biological Chemistry · doi:10.1074/jbc.r100005200 · Cited by 1,474
Cited by
Liu, J., Qiao, S. Z., Budi Hartono, S., & Lu, G. Q. (. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201001252 · Cited by 591
Chiral covalent organic frameworks: design, synthesis and property
Han, X., Yuan, C., Hou, B., Liu, L., Li, H., Liu, Y., & Cui, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00009d · Cited by 478
Catalytic Non‐Enzymatic Kinetic Resolution
Pellissier, H. (2011) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.201100111 · Cited by 353
Xia, Q., Li, Z., Tan, C., Liu, Y., Gong, W., & Cui, Y. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03113 · Cited by 265
Chiral Nanoporous Metal–Metallosalen Frameworks for Hydrolytic Kinetic Resolution of Epoxides
Zhu, C., Yuan, G., Chen, X., Yang, Z., & Cui, Y. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302340b · Cited by 257
Metadata
- Authors
- Yang, H., Zhang, L., Zhong, L., Yang, Q., & Li, C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2007-09-04
- Volume
- 46
- Issue
- 36
- Pages
- 6861-6865
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2147238337
- Cited by
- 210
- References
- 1
- FWCI
- 7.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, H., Zhang, L., Zhong, L., Yang, Q., & Li, C. (2007). Enhanced Cooperative Activation Effect in the Hydrolytic Kinetic Resolution of Epoxides on [Co(salen)] Catalysts Confined in Nanocages. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200701747
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