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Role of Lattice Strain and Defects in Copper Particles on the Activity of Cu/ZnO/Al2O3 Catalysts for Methanol Synthesis
Abstract
On the nature of copper in real methanol synthesis catalysts: Cu/Zn/Al2O3 catalysts with industrially relevant high copper content have been investigated. With the aid of combined TEM (see picture) and XRD analysis, imperfections in the Cu lattice arising from twinning, fault defects, and strain are found to be related to increased activity of the catalysts in methanol synthesis.
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Cites
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Cited by
Centi, G., Quadrelli, E. A., & Perathoner, S. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00056g · Cited by 1,257
A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
Feng, X., Jiang, K., Fan, S., & Kanan, M. W. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00022 · Cited by 460
Metadata
- Authors
- Kasatkin, I., Kurr, P., Kniep, B., Trunschke, A., & Schlögl, R.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2007-09-17
- Volume
- 46
- Issue
- 38
- Pages
- 7324-7327
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4240932991
- Cited by
- 256
- References
- 1
- FWCI
- 3.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kasatkin, I., Kurr, P., Kniep, B., Trunschke, A., & Schlögl, R. (2007). Role of Lattice Strain and Defects in Copper Particles on the Activity of Cu/ZnO/Al2O3 Catalysts for Methanol Synthesis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200702600
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
