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“Nonsolvent” Applications of Ionic Liquids in Biotransformations and Organocatalysis
Abstract
The application of room‐temperature ionic liquids (RTILs) as (co)solvents and/or reagents is well documented. However, RTILS also have “nonsolvent” applications in biotransformations and organocatalysis. Examples are the anchoring of substrates to RTILs; ionic‐liquid‐coated enzymes (ILCE) and enzyme–IL colyophilization; the construction of biocatalytic ternary reaction systems; the combination of enzymes, RTILs, membranes, and (bio)electrochemistry; and ionic‐liquid‐supported organocatalysts. These strategies provide more robust, more efficient, and more enantioselective bio‐ and organocatalysts with many practical applications. As shown herein, RTILs offer a wide range of promising alternatives to conventional chemistry.
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Cites
COLLINS, K. (2004) · Methods · doi:10.1016/j.ymeth.2004.03.021 · Cited by 1,091
H. Davis, J. (2004) · Chemistry Letters · doi:10.1246/cl.2004.1072 · Cited by 1,053
Cited by
Biological Activity of Ionic Liquids and Their Application in Pharmaceutics and Medicine
Egorova, K. S., Gordeev, E. G., & Ananikov, V. P. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00562 · Cited by 1,649
Ionic liquids and catalysis: Recent progress from knowledge to applications
Olivier-Bourbigou, H., Magna, L., & Morvan, D. (2010) · Applied Catalysis A: General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,639
Giernoth, R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200905981 · Cited by 746
Pace, V., Hoyos, P., Castoldi, L., Domínguez de María, P., & Alcántara, A. R. (2012) · ChemSusChem · doi:10.1002/cssc.201100780 · Cited by 699
Self-citationStrategies for Stabilization of Enzymes in Organic Solvents
Stepankova, V., Bidmanova, S., Koudelakova, T., Prokop, Z., Chaloupkova, R., & Damborsky, J. (2013) · ACS Catalysis · doi:10.1021/cs400684x · Cited by 659
Metadata
- Authors
- Domínguez de María, P.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-08-27
- Volume
- 47
- Issue
- 37
- Pages
- 6960-6968
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2162754394
- Cited by
- 227
- References
- 2
- FWCI
- 10.82
- Type
- journal article
- Language
- en
- Open access
- closed
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