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Directing the Structure of Metal–Organic Frameworks by Oriented Surface Growth on an Organic Monolayer
Abstract
Orientation and structure of porous metal–organic frameworks (MOFs) based on iron and 1,4-benzenedicarboxylic acid can be controlled by heterogeneous nucleation on self-assembled monolayers of mercaptohexadecanoic acid (MHDA). Thus, the product of homogeneous nucleation is the MOF Fe-MIL-53, whereas in the same crystallization solution, oriented Fe-MIL-88B grows on a MHDA-functionalized gold surface (see picture).
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Lowenstam, H. A., & Weiner, S. (1989) · doi:10.1093/oso/9780195049770.001.0001 · Cited by 2,090
Taking advantage of disorder: amorphous calcium carbonate and its roles in biomineralization
Addadi, L., Raz, S., & Weiner, S. (2003) · Advanced Materials · doi:10.1002/adma.200300381 · Cited by 1,594
Cited by
Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Thin films of metal–organic frameworks
Zacher, D., Shekhah, O., Wöll, C., & Fischer, R. A. (2009) · Chemical Society Reviews · doi:10.1039/b805038b · Cited by 893
MOF positioning technology and device fabrication
Falcaro, P., Ricco, R., Doherty, C. M., Liang, K., Hill, A. J., & Styles, M. J. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00089g · Cited by 710
Carné-Sánchez, A., Imaz, I., Cano-Sarabia, M., & Maspoch, D. (2013) · Nature Chemistry · doi:10.1038/nchem.1569 · Cited by 678
Structure-Directing Role of Graphene in the Synthesis of Metal−Organic Framework Nanowire
Jahan, M., Bao, Q., Yang, J.-X., & Loh, K. P. (2010) · Journal of the American Chemical Society · doi:10.1021/ja105089w · Cited by 466
Metadata
- Authors
- Scherb, C., Schödel, A., & Bein, T.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-07-14
- Volume
- 47
- Issue
- 31
- Pages
- 5777-5779
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2122281045
- Cited by
- 208
- References
- 2
- FWCI
- 11.81
- Type
- journal article
- Language
- en
- Open access
- closed
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- Scherb, C., Schödel, A., & Bein, T. (2008). Directing the Structure of Metal–Organic Frameworks by Oriented Surface Growth on an Organic Monolayer. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200704034
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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