The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Structure-Directing Role of Graphene in the Synthesis of Metal−Organic Framework Nanowire
Abstract
Graphene can be decorated with functional groups on either side of its basal plane, giving rise to a bifunctional nanoscale building block that can undergo face-to-face assembly. We demonstrate that benzoic acid-functionalized graphene (BFG) can act as a structure-directing template in influencing the crystal growth of metal-organic framework (MOF). BFG is also incorporated into MOF as framework linker. Because of the high density of carboxylic groups on benzoic acid-functionalized graphene, an unusual MOF nanowire that grows in the [220] direction was synthesized. The diameter of the nanowire correlates closely with the lateral dimensions of the BFG. The intercalation of graphene in MOF imparts new electrical properties such as photoelectric transport in the otherwise insulating MOF. The results point to the possibility of using functionalized graphene to synthesize a wide range of structural motifs in MOF with adjustable metrics and properties.
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Cites
The electronic properties of graphene
Castro Neto, A. H., Guinea, F., Peres, N. M. R., Novoselov, K. S., & Geim, A. K. (2009) · Reviews of Modern Physics · doi:10.1103/revmodphys.81.109 · Cited by 24,803
The chemistry of graphene oxide
Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010) · Chem. Soc. Rev. · doi:10.1039/b917103g · Cited by 11,653
Cited by
Jahan, M., Liu, Z., & Loh, K. P. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201300510 · Cited by 1,016
Self-citationZhong, H., Wang, J., Zhang, Y., Xu, W., Xing, W., Xu, D., Zhang, Y., & Zhang, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408990 · Cited by 938
Jiao, L., Zhou, Y.-X., & Jiang, H.-L. (2016) · Chemical Science · doi:10.1039/c5sc04425a · Cited by 798
MOF positioning technology and device fabrication
Falcaro, P., Ricco, R., Doherty, C. M., Liang, K., Hill, A. J., & Styles, M. J. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00089g · Cited by 710
Metal‐Organic Framework‐Based Nanomaterials for Electrocatalysis
Mahmood, A., Guo, W., Tabassum, H., & Zou, R. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600423 · Cited by 632
Metadata
- Authors
- Jahan, M., Bao, Q., Yang, J.-X., & Loh, K. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-23
- Volume
- 132
- Issue
- 41
- Pages
- 14487-14495
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2335010051
- Cited by
- 466
- References
- 2
- FWCI
- 14.56
- Type
- journal article
- Language
- en
- Open access
- closed
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