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Kinetic Gate‐Opening Process in a Flexible Porous Coordination Polymer
Abstract
Open the gate! A porous coordination polymer shows abrupt changes in its adsorption isotherm with guest-dependent gate-opening pressure (see picture). Kinetic analysis reveals that adsorption with structure transformation follows a gate-opening model, in which adsorption proceeds through the formation of an intermediate by a gate-opening process. This process provides a significant difference in onset pressure between similar gas molecules.
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Citations
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Self-citationHighly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks
Choi, H., & Suh, M. P. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200902836 · Cited by 389
Tanaka, D., Henke, A., Albrecht, K., Moeller, M., Nakagawa, K., Kitagawa, S., & Groll, J. (2010) · Nature Chemistry · doi:10.1038/nchem.627 · Cited by 342
Self-citationThermodynamics of Guest-Induced Structural Transitions in Hybrid Organic−Inorganic Frameworks
Coudert, F.-X., Jeffroy, M., Fuchs, A. H., Boutin, A., & Mellot-Draznieks, C. (2008) · Journal of the American Chemical Society · doi:10.1021/ja805129c · Cited by 337
Metadata
- Authors
- Tanaka, D., Nakagawa, K., Higuchi, M., Horike, S., Kubota, Y., Kobayashi, T. C., Takata, M., & Kitagawa, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-05-06
- Volume
- 47
- Issue
- 21
- Pages
- 3914-3918
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2066001826
- Cited by
- 322
- References
- 0
- FWCI
- 19.61
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tanaka, D., Nakagawa, K., Higuchi, M., Horike, S., Kubota, Y., Kobayashi, T. C., Takata, M., & Kitagawa, S. (2008). Kinetic Gate‐Opening Process in a Flexible Porous Coordination Polymer. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200705822
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