The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
Thermodynamics of Guest-Induced Structural Transitions in Hybrid Organic−Inorganic Frameworks
Open accessAbstract
We provide a general thermodynamic framework for the understanding of guest-induced structural transitions in hybrid organic-inorganic materials. The method is based on the analysis of experimental adsorption isotherms. It allows the determination of the free energy differences between host structures involved in guest-induced transitions, especially hard to obtain experimentally. We discuss the general case of adsorption in flexible materials and show how a few key quantities, such as pore volumes and adsorption affinities, entirely determine the phenomenology of adsorption, including the occurrence of structural transitions. On the basis of adsorption thermodynamics, we then propose a taxonomy of guest-induced structural phase transitions and the corresponding isotherms. In particular, we derive generic conditions for observing a double structural transition upon adsorption, often resulting in a two-step isotherm. Finally, we show the wide applicability and the robustness of the model through three case studies of topical hybrid organic-inorganic frameworks: the hysteretic hydrogen adsorption in Co(1,4-benzenedipyrazolate), the guest-dependent gate-opening in Cu(4,4'-bipyridine)(2,5-dihydroxybenzoate)2 and the CO2-induced "breathing" of hybrid material MIL-53.
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Cites
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Functional Porous Coordination Polymers
Kitagawa, S., Kitaura, R., & Noro, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200300610 · Cited by 11,071
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High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO 2 Capture
Banerjee, R., Phan, A., Wang, B., Knobler, C., Furukawa, H., O'Keeffe, M., & Yaghi, O. M. (2008) · Science · doi:10.1126/science.1152516 · Cited by 4,205
Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
Serre, C., Millange, F., Thouvenot, C., Noguès, M., Marsolier, G., Louër, D., & Férey, G. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0276974 · Cited by 1,980
Highly controlled acetylene accommodation in a metal–organic microporous material
Matsuda, R., Kitaura, R., Kitagawa, S., Kubota, Y., Belosludov, R. V., Kobayashi, T. C., Sakamoto, H., Chiba, T., Takata, M., Kawazoe, Y., et al. (2005) · Nature · doi:10.1038/nature03852 · Cited by 1,520
Dynamic porous properties of coordination polymers inspired by hydrogen bonds
Kitagawa, S., & Uemura, K. (2005) · Chemical Society Reviews · doi:10.1039/b313997m · Cited by 1,418
Crystallized Frameworks with Giant Pores: Are There Limits to the Possible?
Férey, G., Mellot-Draznieks, C., Serre, C., & Millange, F. (2005) · Accounts of Chemical Research · doi:10.1021/ar040163i · Cited by 1,327
Self-citationHydrogen Sorption in Functionalized Metal−Organic Frameworks
Rowsell, J. L. C., Millward, A. R., Park, K. S., & Yaghi, O. M. (2004) · Journal of the American Chemical Society · doi:10.1021/ja049408c · Cited by 1,326
Cited by
Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO 2 and CH 4
Couck, S., Denayer, J. F. M., Baron, G. V., Rémy, T., Gascon, J., & Kapteijn, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900555r · Cited by 988
Coudert, F.-X. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00046 · Cited by 528
Self-citationFunctionalized MOFs for Enhanced CO2 Capture
Torrisi, A., Bell, R. G., & Mellot-Draznieks, C. (2010) · Crystal Growth & Design · doi:10.1021/cg100646e · Cited by 293
Self-citationGating effect for gas adsorption in microporous materials—mechanisms and applications
Chen, K., Mousavi, S. H., Singh, R., Snurr, R. Q., Li, G., & Webley, P. A. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00822f · Cited by 133
Metadata
- Authors
- Coudert, F.-X., Jeffroy, M., Fuchs, A. H., Boutin, A., & Mellot-Draznieks, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-09-27
- Volume
- 130
- Issue
- 43
- Pages
- 14294-14302
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2016885611
- Cited by
- 337
- References
- 43
- FWCI
- 12.01
- Type
- journal article
- Language
- en
- Open access
- green
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- Coudert, F.-X., Jeffroy, M., Fuchs, A. H., Boutin, A., & Mellot-Draznieks, C. (2008). Thermodynamics of Guest-Induced Structural Transitions in Hybrid Organic−Inorganic Frameworks. Journal of the American Chemical Society. https://doi.org/10.1021/ja805129c
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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