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Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation
Abstract
The coordinatively unsaturated sites in MIL-101, Cr3(F,OH)(H2O)2O[(O2C)-C6H4-(CO2)]3⋅n H2O (n≈25), having zeotypic giant pores can be selectively functionalized in a way differing from that of mesoporous silica. Metal–organic frameworks, grafted with ethylenediamine or diethylenetriamine on the unsaturated CrIII sites of MIL-101, exhibit remarkably high activities in the Knoevenagel condensation relative to that of the mesophase.
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Citations
Cited by
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Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Direct Capture of CO2 from Ambient Air
Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00173 · Cited by 2,406
Chizallet, C., Lazare, S., Bazer-Bachi, D., Bonnier, F., Lecocq, V., Soyer, E., Quoineaud, A.-A., & Bats, N. (2010) · Journal of the American Chemical Society · doi:10.1021/ja103365s · Cited by 586
Tailored crystalline microporous materials by post-synthesis modification
Valtchev, V., Majano, G., Mintova, S., & Pérez-Ramírez, J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35196j · Cited by 478
Pore Chemistry of Metal–Organic Frameworks
Ji, Z., Wang, H., Canossa, S., Wuttke, S., & Yaghi, O. M. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000238 · Cited by 459
Metadata
- Authors
- Hwang, Y. K., Hong, D., Chang, J., Jhung, S. H., Seo, Y., Kim, J., Vimont, A., Daturi, M., Serre, C., & Férey, G.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-05-09
- Volume
- 47
- Issue
- 22
- Pages
- 4144-4148
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2005693784
- Cited by
- 1,243
- References
- 0
- FWCI
- 38.03
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Hwang, Y. K., Hong, D., Chang, J., Jhung, S. H., Seo, Y., Kim, J., Vimont, A., Daturi, M., Serre, C., & Férey, G. (2008). Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200705998
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