Direct Capture of CO2 from Ambient Air
Open accessAbstract
The increase in the global atmospheric CO2 concentration resulting from over a century of combustion of fossil fuels has been associated with significant global climate change. With the global population increase driving continued increases in fossil fuel use, humanity’s primary reliance on fossil energy for the next several decades is assured. Traditional modes of carbon capture such as precombustion and postcombustion CO2 capture from large point sources can help slow the rate of increase of the atmospheric CO2 concentration, but only the direct removal of CO2 from the air, or “direct air capture” (DAC), can actually reduce the global atmospheric CO2 concentration. The past decade has seen a steep rise in the use of chemical sorbents that are cycled through sorption and desorption cycles for CO2 removal from ultradilute gases such as air. This Review provides a historical overview of the field of DAC, along with an exhaustive description of the use of chemical sorbents targeted at this application. Solvents and solid sorbents that interact strongly with CO2 are described, including basic solvents, supported amine and ammonium materials, and metal–organic frameworks (MOFs), as the primary classes of chemical sorbents. Hypothetical processes for the deployment of such sorbents are discussed, as well as the limited array of technoeconomic analyses published on DAC. Overall, it is concluded that there are many new materials that could play a role in emerging DAC technologies. However, these materials need to be further investigated and developed with a practical sorbent–air contacting process in mind if society is to make rapid progress in deploying DAC as a means of mitigating climate change.
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DAC on zeolites has been studied and most works point at commercial and, in general, aluminosilicate zeolites not being promising adsorbents for this application due to water adsorption.
“DAC on zeolites has been studied and most of the works point at commercial and, in general, aluminosilicate zeolites not being promising adsorbents for this application due to water adsorption.534,537−539”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [534]
Pressure swing adsorption is an industrially used process with low operating costs, high efficiency, and limited footprint.
“For gas product separation, pressure swing adsorption is an industrially used process with low operating costs, high efficiency, and limited footprint.82”
From General Techno-Economic Analysis of CO <sub>2</sub> Electrolysis Systems (2018) · cites this paper as [82]
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- Authors
- Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W.
- Affiliations
- Georgia Institute of Technology , , 311 Ferst Drive , , ,
- Georgia Institute of Technology (US)
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-08-25
- Volume
- 116
- Issue
- 19
- Pages
- 11840-11876
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2508859475
- Semantic Scholar
- 1730cf009126df0e913e24859aaee075b31b6a00
- Cited by
- 2,406
- References
- 238
- Citations by year
- 2026: 325 · 2025: 350 · 2024: 335 · 2023: 281 · 2022: 263 · 2021: 257 · 2020: 223 · 2019: 158 · 2018: 119 · 2017: 87 · 2016: 7
- FWCI
- 11.84
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Chemical Reviews (publishedVersion, other-oa)
- PubMed (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- Basic Energy Sciences (DE-SC0012577)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- direct air capture, CO2 capture, basic solvents, metal-organic frameworks, sorption-desorption cycles, climate change mitigation, techno-economic analysis
- MeSH terms
- Adsorption, Air, Alkalies, Amines, Carbon Dioxide, Coordination Complexes
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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