The DOI matches its Crossref record.
Asymmetric Diels–Alder Reactions of α,β‐Unsaturated Aldehydes Catalyzed by a Diarylprolinol Silyl Ether Salt in the Presence of Water
Abstract
Water, water, everywhere: The title reaction predominantly affords the exo isomer with excellent enantioselectivity (see scheme; TMS=trimethylsilyl). The synthesis can be carried out without organic solvents and provides the products by distillation. Water increases the rate and enantioselectivity of the reaction.
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Citations
Cited by
Liu, Y., Nappi, M., Arceo, E., Vera, S., & Melchiorre, P. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206517s · Cited by 398
Arlegui, A., Soler, B., Galindo, A., Arteaga, O., Canillas, A., Ribó, J. M., El-Hachemi, Z., Crusats, J., & Moyano, A. (2019) · Chemical Communications · doi:10.1039/c9cc05946f · Cited by 27
Metadata
- Authors
- Hayashi, Y., Samanta, S., Gotoh, H., & Ishikawa, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-08-11
- Volume
- 47
- Issue
- 35
- Pages
- 6634-6637
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2089775150
- Cited by
- 170
- References
- 0
- FWCI
- 9.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hayashi, Y., Samanta, S., Gotoh, H., & Ishikawa, H. (2008). Asymmetric Diels–Alder Reactions of α,β‐Unsaturated Aldehydes Catalyzed by a Diarylprolinol Silyl Ether Salt in the Presence of Water. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200801408
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