The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
“If Pigs Could Fly” Chemistry: A Tutorial on the Principle of Microscopic Reversibility
Abstract
Through a glass darkly: Several recent autocatalytic reaction models for the origin of homochirality have suggested ways in which one enantiomer of the product might be reconverted into the other by a recycling reaction in a closed system. These models are revealed to violate the principle of microscopic reversibility, a powerful tool for assessing the plausibility of proposed reaction networks even at far‐from‐equilibrium conditions.magnified image
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Asymmetric autocatalysis and amplification of enantiomeric excess of a chiral molecule
Soai, K., Shibata, T., Morioka, H., & Choji, K. (1995) · Nature · doi:10.1038/378767a0 · Cited by 1,085
On spontaneous asymmetric synthesis
Frank, F. C. (1953) · Biochimica et Biophysica Acta · doi:10.1016/0006-3002(53)90082-1 · Cited by 905
Viedma, C. (2005) · Physical Review Letters · doi:10.1103/physrevlett.94.065504 · Cited by 818
Emergence of a single solid chiral state from a nearly racemic amino acid derivative
Noorduin, W. L., Izumi, T., Millemaggi, A., Leeman, M., Meekes, H., Van Enckevort, W. J. P., Kellogg, R. M., Kaptein, B., Vlieg, E., & Blackmond, D. G. (2008) · Journal of the American Chemical Society · doi:10.1021/ja7106349 · Cited by 459
Self-citationThermodynamic control of asymmetric amplification in amino acid catalysis
Klussmann, M., Iwamura, H., Mathew, S. P., Wells, D. H., Pandya, U., Armstrong, A., & Blackmond, D. G. (2006) · Nature · doi:10.1038/nature04780 · Cited by 396
Self-citationAsymmetric autocatalysis and its implications for the origin of homochirality
Blackmond, D. G. (2004) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0308363101 · Cited by 328
Self-citationEvolution of Solid Phase Homochirality for a Proteinogenic Amino Acid
Viedma, C., Ortiz, J. E., Torres, T. D., Izumi, T., & Blackmond, D. G. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8074506 · Cited by 264
Self-citationComplete Homochirality Induced by Nonlinear Autocatalysis and Recycling
Saito, Y., & Hyuga, H. (2004) · Journal of the Physical Society of Japan · doi:10.1143/jpsj.73.33 · Cited by 103
Demonstration of spontaneous chiral symmetry breaking in asymmetric Mannich and Aldol reactions
Mauksch, M., Tsogoeva, S. B., Wei, S., & Martynova, I. M. (2007) · Chirality · doi:10.1002/chir.20474 · Cited by 89
Mauksch, M., & Tsogoeva, S. B. (2008) · ChemPhysChem · doi:10.1002/cphc.200800226 · Cited by 46
Cited by
Bissette, A. J., & Fletcher, S. P. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201303822 · Cited by 403
Chemically Fueled Self‐Assembly in Biology and Chemistry
Das, K., Gabrielli, L., & Prins, L. J. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202100274 · Cited by 336
Mastering the non-equilibrium assembly and operation of molecular machines
Pezzato, C., Cheng, C., Stoddart, J. F., & Astumian, R. D. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00068e · Cited by 300
Buhse, T., Cruz, J.-M., Noble-Terán, M. E., Hochberg, D., Ribó, J. M., Crusats, J., & Micheau, J.-C. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00819 · Cited by 189
Autocatalytic Models for the Origin of Biological Homochirality
Blackmond, D. G. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00557 · Cited by 182
Self-citation
Metadata
- Authors
- Blackmond, D. G.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2009-03-24
- Volume
- 48
- Issue
- 15
- Pages
- 2648-2654
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2108229334
- Cited by
- 186
- References
- 10
- FWCI
- 4.52
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: “If Pigs Could Fly” Chemistry: A Tutorial on the Principle of Microscopic Reversibility. https://app.cochat.ai/papers/10.1002/anie.200804566
- The paper
- Blackmond, D. G. (2009). “If Pigs Could Fly” Chemistry: A Tutorial on the Principle of Microscopic Reversibility. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200804566
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.