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Copper‐Mediated Coupling of 1,1‐Dibromo‐1‐alkenes with Nitrogen Nucleophiles: A General Method for the Synthesis of Ynamides
Abstract
Mild reaction conditions are the advantage of the title reaction, which allows straightforward entry to a variety of ynamides starting from readily available 1,1‐dibromo‐1‐alkenes, which act as attractive alkynylating agents (see scheme; EWG=electron‐withdrawing group, DMF=N,N‐dimethylformamide).magnified image
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Cited by
Ynamides: Versatile Tools in Organic Synthesis
Evano, G., Coste, A., & Jouvin, K. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200905817 · Cited by 812
Self-citationThe Complementary Competitors: Palladium and Copper in C–N Cross-Coupling Reactions
Beletskaya, I. P., & Cheprakov, A. V. (2012) · Organometallics · doi:10.1021/om300683c · Cited by 454
Metadata
- Authors
- Coste, A., Karthikeyan, G., Couty, F., & Evano, G.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2009-05-26
- Volume
- 48
- Issue
- 24
- Pages
- 4381-4385
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W1979725740
- Cited by
- 211
- References
- 0
- FWCI
- 10.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- Coste, A., Karthikeyan, G., Couty, F., & Evano, G. (2009). Copper‐Mediated Coupling of 1,1‐Dibromo‐1‐alkenes with Nitrogen Nucleophiles: A General Method for the Synthesis of Ynamides. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200901099
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