The DOI matches its Crossref record; 67 of the 67 references it cites were found in a registry or an index.
The Complementary Competitors: Palladium and Copper in C–N Cross-Coupling Reactions
Abstract
The C–N cross-coupling chemistry intensely developed since the late 1990s has supplied synthesists with an overwhelming number of methods to effectively combine carbon and nitrogen residues. This new chemistry relies on complexes of mainly two metals, copper and palladium, used as catalysts or stoichiometric agents. The development of new methods has revealed both similarities and differences in the principles used for the design of new catalytic systems and analysis of their reactivity and selectivity. The discussion of cross-coupling chemistry of these two metals can be performed within a common mechanistic paradigm, helping to elucidate the key factors governing the behavior of the transition-metal complexes involved.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824
The Heck Reaction as a Sharpening Stone of Palladium Catalysis
Beletskaya, I. P., & Cheprakov, A. V. (2000) · Chemical Reviews · doi:10.1021/cr9903048 · Cited by 3,902
Self-citationEquilibrium acidities in dimethyl sulfoxide solution
Bordwell, F. G. (1988) · Accounts of Chemical Research · doi:10.1021/ar00156a004 · Cited by 2,874
Modern Synthetic Methods for Copper‐Mediated C(aryl)O, C(aryl)N, and C(aryl)S Bond Formation
Ley, S. V., & Thomas, A. W. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200300594 · Cited by 2,554
Catalysts for Suzuki−Miyaura Coupling Processes: Scope and Studies of the Effect of Ligand Structure
Barder, T. E., Walker, S. D., Martinelli, J. R., & Buchwald, S. L. (2005) · Journal of the American Chemical Society · doi:10.1021/ja042491j · Cited by 1,796
C−F Bond Activation in Organic Synthesis
Amii, H., & Uneyama, K. (2009) · Chemical Reviews · doi:10.1021/cr800388c · Cited by 1,549
Copper‐Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights
Wendlandt, A. E., Suess, A. M., & Stahl, S. S. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103945 · Cited by 1,292
Diaryliodonium Salts: A Journey from Obscurity to Fame
Merritt, E. A., & Olofsson, B. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200904689 · Cited by 1,188
A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines
Guram, A. S., Rennels, R. A., & Buchwald, S. L. (1995) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199513481 · Cited by 1,070
Klapars, A., Antilla, J. C., Huang, X., & Buchwald, S. L. (2001) · Journal of the American Chemical Society · doi:10.1021/ja016226z · Cited by 1,021
Cited by
Egorova, K. S., & Ananikov, V. P. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201603777 · Cited by 490
Metadata
- Authors
- Beletskaya, I. P., & Cheprakov, A. V.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-11-14
- Volume
- 31
- Issue
- 22
- Pages
- 7753-7808
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2053129143
- Cited by
- 454
- References
- 67
- FWCI
- 19.25
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: The Complementary Competitors: Palladium and Copper in C–N Cross-Coupling Reactions. https://app.cochat.ai/papers/10.1021/om300683c
- The paper
- Beletskaya, I. P., & Cheprakov, A. V. (2012). The Complementary Competitors: Palladium and Copper in C–N Cross-Coupling Reactions. Organometallics. https://doi.org/10.1021/om300683c
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
