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Et2SBr⋅SbCl5Br: An Effective Reagent for Direct Bromonium‐Induced Polyene Cyclizations
Abstract
It's all about reactivity: Although bromonium-induced cation–π cyclizations are commonly utilized by nature to fashion six-membered rings from a diverse set of polyene precursors, no general laboratory method exists that can achieve the same breadth of substrate scope. An easily synthesized and handled reagent is described (see scheme) that is capable of directly, broadly, and rapidly effecting such reactions in good yield with a variety of geraniol, farnesol, and nerol derivatives.
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Cited by
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Welsch, M. E., Snyder, S. A., & Stockwell, B. R. (2010) · Current Opinion in Chemical Biology · doi:10.1016/j.cbpa.2010.02.018 · Cited by 1,509
Self-citationChemistry and Biology of Resveratrol-Derived Natural Products
Keylor, M. H., Matsuura, B. S., & Stephenson, C. R. J. (2015) · Chemical Reviews · doi:10.1021/cr500689b · Cited by 366
Metadata
- Authors
- Snyder, S. A., & Treitler, D. S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2009-09-30
- Volume
- 48
- Issue
- 42
- Pages
- 7899-7903
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2123773613
- Cited by
- 164
- References
- 0
- FWCI
- 5.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Snyder, S. A., & Treitler, D. S. (2009). Et2SBr⋅SbCl5Br: An Effective Reagent for Direct Bromonium‐Induced Polyene Cyclizations. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200903834
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
