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Surface Chemistry of Metal–Organic Frameworks at the Liquid–Solid Interface
Abstract
Metal–organic frameworks (MOFs) are a fascinating class of novel inorganic–organic hybrid materials. They are essentially based on classic coordination chemistry and hold much promise for unique applications ranging from gas storage and separation to chemical sensing, catalysis, and drug release. The evolution of the full innovative potential of MOFs, in particular for nanotechnology and device integration, however requires a fundamental understanding of the formation process of MOFs. Also necessary is the ability to control the growth of thin MOF films and the positioning of size‐ and shape‐selected crystals as well as MOF heterostructures on a given surface in a well‐defined and oriented fashion. MOFs are solid‐state materials typically formed by solvothermal reactions and their crystallization from the liquid phase involves the surface chemistry of their building blocks. This Review brings together various key aspects of the surface chemistry of MOFs.
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Cites
The hydrothermal synthesis of zeolites: Precursors, intermediates and reaction mechanism
Cundy, C. S., & Cox, P. A. (2005) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2005.02.016 · Cited by 1,590
Cited by
Metal–organic frameworks for membrane-based separations
Denny, M. S., Moreton, J. C., Benz, L., & Cohen, S. M. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.78 · Cited by 820
MOF positioning technology and device fabrication
Falcaro, P., Ricco, R., Doherty, C. M., Liang, K., Hill, A. J., & Styles, M. J. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00089g · Cited by 710
Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks
Ni, Z.-P., Liu, J.-L., Hoque, M. N., Liu, W., Li, J.-Y., Chen, Y.-C., & Tong, M.-L. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2016.12.002 · Cited by 448
The surface chemistry of metal–organic frameworks
McGuire, C. V., & Forgan, R. S. (2015) · Chemical Communications · doi:10.1039/c4cc04458d · Cited by 396
Li, L., Xiang, S., Cao, S., Zhang, J., Ouyang, G., Chen, L., & Su, C.-Y. (2013) · Nature Communications · doi:10.1038/ncomms2757 · Cited by 394
Metadata
- Authors
- Zacher, D., Schmid, R., Wöll, C., & Fischer, R. A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2010-12-28
- Volume
- 50
- Issue
- 1
- Pages
- 176-199
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2011012000
- Cited by
- 318
- References
- 1
- FWCI
- 22.71
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zacher, D., Schmid, R., Wöll, C., & Fischer, R. A. (2011). Surface Chemistry of Metal–Organic Frameworks at the Liquid–Solid Interface. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201002451
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