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A Well‐Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides

Open access
Federsel, Christopher, Boddien, Albert, Jackstell, Ralf, Jennerjahn, Reiko, Dyson, Paul J., Scopelliti, Rosario, Laurenczy, Gabor, Beller, Matthias·2010·Angewandte Chemie International Edition

Abstract

A will of iron: An active well-defined iron complex (see structure; gray C, white H, yellow B, green F, brown Fe, pink P) catalyzes the title reaction (see scheme). The iron-catalyzed reduction of readily available bicarbonates to formates has also been demonstrated for the first time. This reaction could be an important step in the use of CO2 for hydrogen storage.

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Metadata

Authors
Federsel, C., Boddien, A., Jackstell, R., Jennerjahn, R., Dyson, P. J., Scopelliti, R., Laurenczy, G., & Beller, M.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2010-11-10
Volume
49
Issue
50
Pages
9777-9780
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2110659651
Cited by
542
References
0
FWCI
19.04
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: A Well‐Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides. https://app.cochat.ai/papers/10.1002/anie.201004263
The paper
Federsel, C., Boddien, A., Jackstell, R., Jennerjahn, R., Dyson, P. J., Scopelliti, R., Laurenczy, G., & Beller, M. (2010). A Well‐Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201004263

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.