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Thermal Amorphization of Zeolitic Imidazolate Frameworks
Abstract
Each the same: A stable, recoverable, amorphous phase (see topology model) was produced by heating each of four different zeolitic imidazolate frameworks ZIF-1, -3, -4, and Co-ZIF-4. By comparing nanoindentation results, density measurements, and X-ray total scattering results, it is concluded that the structure of the amorphous phase is equivalent in each case. Amorphization was only observed in ZIFs encompassing unsubstituted imidazolate ligands.
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Citations
Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Tan, J. C., Bennett, T. D., & Cheetham, A. K. (2010) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1003205107 · Cited by 552
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Cited by
Amorphous Metal–Organic Frameworks
Bennett, T. D., & Cheetham, A. K. (2014) · Accounts of Chemical Research · doi:10.1021/ar5000314 · Cited by 678
Self-citationMetal-organic frameworks for advanced drug delivery
He, S., Wu, L., Li, X., Sun, H., Xiong, T., Liu, J., Huang, C., Xu, H., Sun, H., Chen, W., et al. (2021) · Acta Pharmaceutica Sinica B · doi:10.1016/j.apsb.2021.03.019 · Cited by 528
Hybrid glasses from strong and fragile metal-organic framework liquids
Bennett, T. D., Tan, J.-C., Yue, Y., Baxter, E., Ducati, C., Terrill, N. J., Yeung, H. H. M., Zhou, Z., Chen, W., Henke, S., et al. (2015) · Nature Communications · doi:10.1038/ncomms9079 · Cited by 398
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Metadata
- Authors
- Bennett, T. D., Keen, D. A., Tan, J., Barney, E. R., Goodwin, A. L., & Cheetham, A. K.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2011-02-25
- Volume
- 50
- Issue
- 13
- Pages
- 3067-3071
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2115792814
- Cited by
- 178
- References
- 2
- FWCI
- 5.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bennett, T. D., Keen, D. A., Tan, J., Barney, E. R., Goodwin, A. L., & Cheetham, A. K. (2011). Thermal Amorphization of Zeolitic Imidazolate Frameworks. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201007303
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